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Interfacial irregularity induced by hydrogen bonds at the interface in immiscible polymer blends
| Content Provider | Scilit |
|---|---|
| Author | Kobori, Yuka Yasumitsu, Rei Akiba, Isamu Akiyama, Saburo Sano, Hironari |
| Copyright Year | 2004 |
| Abstract | Effects of interactions at the interface on the morphologies of immiscible polymer blends were investigated using linear low-density polyethylene/poly(4- vinylphenol) (LLDPE/PVPh) and LLDPE/poly(methyl methacrylate) (LLDPE/PMMA) blends containing polyethylene-block-PMMA (PE-b-PMMA). In the case of LLDPE/ PMMA/PE-b-PMMA blends, in which there is no specific interaction at the interface, shapes of dispersed droplets were maintained and sizes were simply diminished with increasing PE-b-PMMA content. On the other hand, in the case of LLDPE/ PVPh/PE-b-PMMA, in which hydrogen bonds are formed between PVPh and PMMA blocks at the interface, we found irregularly undulated phase boundaries. |
| Related Links | http://www.degruyter.com/dg/viewarticle.fullcontentlink:pdfeventlink/$002fj$002fepoly.2004.4.issue-1$002fepoly.2004.4.1.34$002fepoly.2004.4.1.34.pdf?t:ac=j$002fepoly.2004.4.issue-1$002fepoly.2004.4.1.34$002fepoly.2004.4.1.34.xml |
| Ending Page | 39 |
| Page Count | 6 |
| Starting Page | 34 |
| ISSN | 21974586 |
| e-ISSN | 16187229 |
| DOI | 10.1515/epoly.2004.4.1.34 |
| Journal | e-Polymers |
| Issue Number | 1 |
| Volume Number | 4 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 2004-12-01 |
| Access Restriction | Open |
| Subject Keyword | E-polymers Polymer Science Hydrogen Bonds Immiscible Polymer Polymer Blends Blocks Block Pmma Journal: e-Polymers, Vol- 4, Issue- 1 |
| Content Type | Text |
| Resource Type | Article |