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Beiträge zur Chemie des Bors, CVII [1] Über Darstellung und Struktur eines tetraborylierten Hydrazins / Contributions to the Chemistry of Boron, CVII [1] On the Preparation and Structure of a Tetraborylated Hydrazine
| Content Provider | Scilit |
|---|---|
| Author | Bharara, P. C. Nöth, H. |
| Copyright Year | 1979 |
| Abstract | N,N,N′-Tris- and N,N,N′,N′-tetrakis(1,3-dimethyl-1,3,2-diazaborolidinyl)hydrazine (4)were prepared via N,N′-lithiated N,N′-bis(1,3-dimethyl-1,3,2-diazaborolidinyl)hydrazine. 4 crystallizes monoclinic.The N-N axes of the 4 molecules coincide with the crystallo-graphic twofold axes. Its N-N bond is rather long(146.4qm and the ring BN bonds are shorter than the BN bond to the hydrazine nitrogen atoms. This indicates preferential electronic saturation of the boron atoms via ring BN II bonding. |
| Related Links | http://www.degruyter.com/downloadpdf/j/znb.1979.34.issue-10/znb-1979-1002/znb-1979-1002.xml |
| Ending Page | 1357 |
| Page Count | 6 |
| Starting Page | 1352 |
| ISSN | 09320776 |
| e-ISSN | 18657117 |
| DOI | 10.1515/znb-1979-1002 |
| Journal | Zeitschrift für Naturforschung B |
| Issue Number | 10 |
| Volume Number | 34 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 1979-10-01 |
| Access Restriction | Open |
| Subject Keyword | Zeitschrift Für Naturforschung B Inorganic Chemistry Nitrogen Hydrazine Cvii Structure Axes Atoms Diazaborolidinyl Dimethyl Bis Preferential Journal: Zeitschrift für Naturforschung B, Issue- 7-8 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |