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Bis[dicarbonyl(cyclopentadienyl)ruthenium(I)] Komplexe / Bis[dicarbonyl(cyclopentadienyl)ruthenium(I)] Complexes
| Content Provider | Scilit |
|---|---|
| Author | Schumann, Herbert Stenz, Susanne Girgsdies, Frank Mühle, Stefan H. |
| Copyright Year | 2002 |
| Abstract | Ru3(CO)12 reacts with 1-tert-butyl-2,4-cyclopentadiene (1), 1-trimethylsilyl-2,4-cyclopentadiene (2), 1-tert-butyl-3-methyl-2,4-cyclopentadiene (3), 1,3-di(tert-butyl)-2,4-cyclopentadiene (4), 1-iso-propyl-2,3,4,5-tetramethyl-2,4-cyclopentadiene (5), 1-tert-butyl-2,3,4,5-tetramethyl- 2,4-cyclopentadiene (6), 1-phenyl-2,3,4,5-tetramethyl-2,4-cyclopentadiene (7), 2,5- diphenyl-2,4-cyclopentadiene (8), or 2,3,4,5-tetraphenyl-2,4-cyclopentadiene (9) with formation of the corresponding bis[dicarbonyl(cyclopentadienyl) ruthenium(I)] complexes [RuCp# (CO)2]2 1a to 9a. The 1H and 13C NMR spectra of the new compounds 3a and 5a to 9a as well as the single crystal X-ray structures of 1a, 4a, 5a, 7a, 8a, and 9a are reported and discussed |
| Related Links | http://www.degruyter.com/downloadpdf/j/znb.2002.57.issue-9/znb-2002-0908/znb-2002-0908.xml |
| Ending Page | 1026 |
| Page Count | 10 |
| Starting Page | 1017 |
| ISSN | 09320776 |
| e-ISSN | 18657117 |
| DOI | 10.1515/znb-2002-0908 |
| Journal | Zeitschrift für Naturforschung B |
| Issue Number | 9 |
| Volume Number | 57 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 2002-09-01 |
| Access Restriction | Open |
| Subject Keyword | Zeitschrift Für Naturforschung B Inorganic Chemistry Ruthenium Complexes Cyclopentadienylruthenium Complexes Rutheniumcarbonyl Complexes Journal: Zeitschrift für Naturforschung B, Issue- 231 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |