NDLI: Selective Hydrogenation of 4’,4”(5”)-Di-Tert-Butyldibenzo-18-Crown-6 Ether over Rh/γ-Al2O3 Nanocatalyst

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Selective Hydrogenation of 4’,4”(5”)-Di-Tert-Butyldibenzo-18-Crown-6 Ether over Rh/γ-Al2O3 Nanocatalyst

Content Provider	Scilit
Author	Suryawanshi, Yogeshwar R. Chakraborty, Mousumi Jauhari, Smita Mukhopadhyay, Sulekha Shenoy, Kalsanka T.
Copyright Year	2017
Abstract	Rh/γ-Al₂O₃ nanocatalysts with different metal loading were synthesized by two different techniques i. e. microemulsion and microwave irradiated solvothermal technique. Synthesized nanocatalysts were then successfully implemented for the hydrogenation of 4’,4”(5”)-di-tert-butyldibenzo-18-crown-6 ether (DTBuB18C6) at 70 bar, 353–393 K temperature and 5 h. It was observed that 3 wt% nanocatalyst obtained by microemulsion technique exhibited higher catalytic activity and resulted 40 % conversion with high selectivity towards cis-syn-cis di-tert-dicyclohexano-18-crown-6ether (CSC DTBuCH18C6).
Related Links	http://www.degruyter.com/downloadpdf/j/ijcre.2017.15.issue-1/ijcre-2015-0204/ijcre-2015-0204.xml
ISSN	21945748
e-ISSN	15426580
DOI	10.1515/ijcre-2015-0204
Journal	International Journal of Chemical Reactor Engineering
Issue Number	1
Volume Number	15
Language	English
Publisher	Walter de Gruyter GmbH
Publisher Date	2017-01-01
Access Restriction	Open
Subject Keyword	International Journal of Chemical Reactor Engineering Organic Chemistry Rohdium Nanocatalyst Di-tert-butyldibenzo-18-crown-6 Ether Selective Hydrogenation Microwave Irradiation Di-tert-dicyclohexano-18-crown-6 Ether. Journal: International Journal of Chemical Reactor Engineering, Vol- 15
Content Type	Text
Resource Type	Article
Subject	Chemical Engineering

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