NDLI: Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia

Content Provider	Scilit
Author	Müller, Matthias Buchner, Magnus R.
Copyright Year	2020
Abstract	Beryllium metal was dissolved in liquid ammonia at ambient temperature through addition of alkali metals. Thereby, the amidoberyllates Cs[Be(NH₂)₃], [Na₄ (NH₂)₂][Be(NH₂)₄] and K₄[Be₂O(NH₂)₄][Be(NH₂)₃]₂ were isolated and structurally characterized via single crystal X-ray diffraction. In the case of Li we were able to synthesize Be(NH₂)₂ at ambient temperature. We present the first example of a [Be(NH₂)₄]²⁻ anion as well as the first oxyamidoberyllate anion [Be₂O(NH₂)₄]²⁻.
Related Links	http://www.degruyter.com/downloadpdf/j/znb.ahead-of-print/znb-2019-0215/znb-2019-0215.xml
Ending Page	489
Page Count	7
Starting Page	483
ISSN	09320776
e-ISSN	18657117
DOI	10.1515/znb-2019-0215
Journal	Zeitschrift für Naturforschung B
Issue Number	5
Volume Number	75
Language	English
Publisher	Walter de Gruyter GmbH
Publisher Date	2020-02-18
Access Restriction	Open
Subject Keyword	Zeitschrift Für Naturforschung B Characterization and Testing of Materials Alkali Metal Ammonia Beryllate Beryllium Journal: Zeitschrift für Naturforschung B, Issue- 5
Content Type	Text
Resource Type	Article
Subject	Chemistry

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Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia