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Making and breaking of phosphorus–phosphorus bonds
| Content Provider | Scilit |
|---|---|
| Author | Grell, Toni Yufanyi, Divine Mbom Adhikari, Anup Kumar Sárosi, Menyhárt-Botond Lönnecke, Peter Hey-Hawkins, Evamarie |
| Copyright Year | 2018 |
| Abstract | In contrast to their mostly unstable isolobal carbon counterparts, oligophosphanide anions, such as M(cyclo-P5 t Bu4) (M=Li, Na) and M2(P4R4) [M=Na, K; R=Ph, t Bu, 2,4,6-Me3C6H2 (Mes)], have unique features, depending on their composition and structure, and are highly suitable building blocks for the synthesis of phosphorus-rich metal compounds. However, alkali metal oligophosphanediides are highly reactive and highly reducing, and a major problem is their tendency for disproportionation in reactions with electrophiles. This, however, can also give rise to a fascinating chemistry of making and breaking of P–P bonds. On the other hand, neutral cyclooligophosphines, such as cyclo-(P5Ph5), are suitable stable ligands for the formation of phosphorus-rich metal complexes. |
| Related Links | http://www.degruyter.com/downloadpdf/j/pac.ahead-of-print/pac-2018-1013/pac-2018-1013.xml |
| Ending Page | 111 |
| Page Count | 9 |
| Starting Page | 103 |
| ISSN | 00334545 |
| e-ISSN | 13653075 |
| DOI | 10.1515/pac-2018-1013 |
| Journal | Pure and Applied Chemistry |
| Issue Number | 1 |
| Volume Number | 91 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 2018-12-20 |
| Access Restriction | Open |
| Subject Keyword | Pure and Applied Chemistry Inorganic Chemistry Icpc-22 Oligophosphanides Oligophosphines P-ligands Phosphorus Transition Metal Complexes Journal: Pure and Applied Chemistry, Issue- 7 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
