NDLI: RAFT Polymerization of Styrene Using Dithioester with Anthracene Z Group as Chain Transfer Agent

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RAFT Polymerization of Styrene Using Dithioester with Anthracene Z Group as Chain Transfer Agent

Content Provider	Scilit
Author	Nianchen, Zhou Jian, Zhu Zhengbiao, Zhang Xiulin, Zhu
Copyright Year	2007
Abstract	A novel dithioester, bearing anthracene as Z group, benzyl anthracene-10-carbodithioate (BAC) was successfully synthesized and used as the RAFT agent for the RAFT polymerizations of styrene (St). The results indicated that the polymerization presented the characteristics of “living”/controlled radical polymerization. ¹H NMR characterization of obtained polystyrene confirmed that most of the polymer chains were end-capped by the anthracene moiety. The successful chain extension experiment further demonstrated the “living” character of the polymer. The fluorescence investigation of the polymers contained an anthrancene moiety of BAC in the chain end expressed enhanced fluorescence property than that of BAC in CHCl₃ solution.
Related Links	http://www.degruyter.com/downloadpdf/j/epoly.2007.7.issue-1/epoly.2007.7.1.1599/epoly.2007.7.1.1599.xml http://www.degruyter.com/dg/viewarticle.fullcontentlink:pdfeventlink/$002fj$002fepoly.2007.7.issue-1$002fepoly.2007.7.1.1599$002fepoly.2007.7.1.1599.pdf?t:ac=j$002fepoly.2007.7.issue-1$002fepoly.2007.7.1.1599$002fepoly.2007.7.1.1599.xml
Ending Page	1608
Page Count	10
Starting Page	1599
ISSN	21974586
e-ISSN	16187229
DOI	10.1515/epoly.2007.7.1.1599
Journal	e-Polymers
Issue Number	1
Volume Number	7
Language	English
Publisher	Walter de Gruyter GmbH
Publisher Date	2007-12-01
Access Restriction	Open
Subject Keyword	E-polymers Polymer Science Polymer Fluorescence Raft Chain Anthracene Styrene Bac Dithioester Moiety Journal: e-Polymers, Vol- 7
Content Type	Text
Resource Type	Article

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