NDLI: Synthesis and thermal properties of triblock copolymers of methyl methacrylate using combination of anionic and controlled radical polymerization: Poly(methyl methacrylate) center block bearing different microstructures

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Synthesis and thermal properties of triblock copolymers of methyl methacrylate using combination of anionic and controlled radical polymerization: Poly(methyl methacrylate) center block bearing different microstructures

Content Provider	Scilit
Author	Song, Zhengji Pelletier, Carole Qi, Yinghua Ahmed, Jasim Varshney, Sunil K. Mazumder, M. A. Jafar
Copyright Year	2012
Abstract	ABA and/or ABC type triblock copolymers were synthesized by living anionic and controlled radical polymerization in which poly(methyl methacrylate) was used as central block. The structural composition of these block copolymers were determined by ¹H NMR. The block length/molecular weight and microstructure of these polymers were measured by SEC. The microstructure of resultant central alkyl methacrylate block can be tailored from highly syndiotactic to highly isotactic structure by varying the solvent and/or initiator. The thermal and rheological properties of center poly(methyl methacrylate) block and poly(styreneb- methyl methacrylate-b- styrene) tri block copolymers were studied in detail.
Related Links	http://www.degruyter.com/downloadpdf/j/epoly.2012.12.issue-1/epoly.2012.12.1.788/epoly.2012.12.1.788.xml http://www.degruyter.com/dg/viewarticle.fullcontentlink:pdfeventlink/$002fj$002fepoly.2012.12.issue-1$002fepoly.2012.12.1.788$002fepoly.2012.12.1.788.pdf?t:ac=j$002fepoly.2012.12.issue-1$002fepoly.2012.12.1.788$002fepoly.2012.12.1.788.xml
Ending Page	802
Page Count	15
Starting Page	788
ISSN	21974586
e-ISSN	16187229
DOI	10.1515/epoly.2012.12.1.788
Journal	e-Polymers
Issue Number	1
Volume Number	12
Language	English
Publisher	Walter de Gruyter GmbH
Publisher Date	2012-12-01
Access Restriction	Open
Subject Keyword	E-polymers Polymer Science Methyl Methacrylate Thermal Microstructure Block Anionic Radical Structural Poly Journal: e-Polymers, Vol- 12, Issue- 1
Content Type	Text
Resource Type	Article

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