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Multifunctional organic polymeric catalysts and reagents
| Content Provider | Scilit |
|---|---|
| Author | Lu, Jinni Toy, Patrick H. |
| Copyright Year | 2012 |
| Abstract | A series of polystyrenes bearing multiple different functional groups has been synthesized, and these materials have been used as catalysts and reagents in a variety of organic reactions. Polymers functionalized with various combinations of amine, phenol, phosphine, and thiourea groups have been prepared in both non-cross-linked (soluble) and cross-linked (insoluble) formats. Reactions catalyzed by these polymers include Morita–Baylis–Hillman (MBH), alkyne to 1,3-diene isomerization, and decarboxylative Doebner–Knoevenagel reactions. Furthermore, Wittig and tandem Wittig/reduction reactions have been performed using heterogeneous polymeric reagents possessing a combination of amine and phosphine groups. |
| Related Links | http://hub.hku.hk/bitstream/10722/185712/1/Content.pdf https://core.ac.uk/download/pdf/38025713.pdf http://www.iupac.org/publications/pac/85/3/0543/pdf/ |
| Ending Page | 556 |
| Page Count | 14 |
| Starting Page | 543 |
| ISSN | 00334545 |
| e-ISSN | 13653075 |
| DOI | 10.1351/pac-con-12-04-13 |
| Journal | Pure and Applied Chemistry |
| Issue Number | 3 |
| Volume Number | 85 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 2012-09-10 |
| Access Restriction | Open |
| Subject Keyword | Pure and Applied Chemistry Organic Chemistry Organocatalysis Journal: Pure and Applied Chemistry, Vol- 85 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
