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Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
| Content Provider | Scilit |
|---|---|
| Author | Bădoiu, Andrei Brinkmann, Yasmin Viton, Florian Kündig, E. Peter |
| Copyright Year | 2008 |
| Abstract | Highly tuned, one-point binding chiral iron and ruthenium complexes selectively coordinate and activate α,β-unsaturated aldehydes and ketones toward asymmetric catalytic Diels-Alder cycloaddition reactions. Here we focus on the application of these transition-metal Lewis acids to asymmetric catalytic 1,3-dipolar cycloaddition reaction between enals and cyclic and acyclic nitrones as well as aryl nitrile oxides to give isoxazolidines and isoxazolines, respectively. |
| Related Links | http://doc.rero.ch/record/301625/files/pac200880051013.pdf http://www.iupac.org/publications/pac/80/5/1013/pdf/ |
| Ending Page | 1018 |
| Page Count | 6 |
| Starting Page | 1013 |
| ISSN | 00334545 |
| e-ISSN | 13653075 |
| DOI | 10.1351/pac200880051013 |
| Journal | Pure and Applied Chemistry |
| Issue Number | 5 |
| Volume Number | 80 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 2008-01-01 |
| Access Restriction | Open |
| Subject Keyword | Pure and Applied Chemistry Organic Chemistry Asymmetric Lewis Dipolar Cycloaddition Ruthenium Isoxazolines Coordinate Give Chiral Aryl Journal: Pure and Applied Chemistry, Issue- 2 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |