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Ternary and quaternary metal nitrides: A new challenge for solid state chemistry
| Content Provider | Scilit |
|---|---|
| Author | Kniep, Rüdiger |
| Copyright Year | 1997 |
| Abstract | The crystal chemistry of ternary and quaternary phases of the systems A/AE - TE - N (A = alkali metal; AE = alkaline earth metal; TE = transition element) is pre- dominantly characterized by the presence and formation of complex nitridometalate anions. A suitable classification of the nitrido-compound s is based on the correlation between coordination-num bers (TE), oxidation s tates (TE) and the specific structural c haracteristics of the a nionic partial structures. Introduction and preparative aspects Compared with the l arge number of well-known and well- investigated oxometalates the crystal chemistry and physics of nitridometalates is rather young and just at the beginning. The particular i nterest in nitridometalate compounds is mainly raised by the h igh polarizability o f the nitride ion which is expected to cause specific properties in structure and bonding relations. |
| Related Links | http://www.degruyter.com/downloadpdf/j/pac.1997.69.issue-1/pac199769010185/pac199769010185.xml |
| Ending Page | 192 |
| Page Count | 8 |
| Starting Page | 185 |
| ISSN | 00334545 |
| e-ISSN | 13653075 |
| DOI | 10.1351/pac199769010185 |
| Journal | Pure and Applied Chemistry |
| Issue Number | 1 |
| Volume Number | 69 |
| Language | English |
| Publisher | Walter de Gruyter GmbH |
| Publisher Date | 1997-01-01 |
| Access Restriction | Open |
| Subject Keyword | Pure and Applied Chemistry Crystallography Alkali Metals Alkaline Earth Metal Crystal Chemistry Journal: Pure and Applied Chemistry, Issue- 3-4 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
