NOTIZEN. Zur Reaktion von PhSSiMe3 mit [CoCl2(PPh3)2] und (NBu4)[CoCl3(PPh3)]. Die Kristallstrukturen von (NBu4)2[Co4(SPh)6Cl4], [Co4(SPh)6Cl2(POPh3)(PPh3)] und (NBu4) [Mn2(SPh)3(CO)6] / Reaction of PhSSiMe3 with [CoCl2(PPh3)2] and (NBu4)[CoCl3(PPh3)]. The Crystal Structures of (NBu4)2[Co4(SPh)6Cl4], [Co4(SPh)6CL(POPh3)(PPh3)] and (NBu4)[Mn2(SPh)3(CO)6]

Content Provider	Scilit
Author	Fenske, Dieter Meyer, J. Merzweiler, K.
Copyright Year	1987
Abstract	(NBu4)2[Co4(SPh)6Cl4] (1) and [Co4(SPh)6CU(PPh3)2] (2) are prepared by the reaction of (NBu4)[CoCl3(PPh3)] and [CoCl2(PPh3)2] with PhSSiMe3 in toluene solution. The overall description of the Co4S6Cl4 core is that o f a nearly regular Co4-tetrahedron inscribed in an irregular octahedron of the bridging S atoms resulting in an “adamantane” type cage. 1 reacts with Na[Mn(CO)5] to form the dinuclear complex (NBu4)[Mn2(SPh)3(CO)6] (4). Each Mn atom is bound to three CO and three μ2-SPh ligands. The Mn-Mn contact (318.5 pm) does not indicate metal-metal bonding.
Related Links	http://www.degruyter.com/downloadpdf/j/znb.1987.42.issue-9/znb-1987-0924/znb-1987-0924.xml
Ending Page	1212
Page Count	6
Starting Page	1207
ISSN	09320776
e-ISSN	18657117
DOI	10.1515/znb-1987-0924
Journal	Zeitschrift für Naturforschung B
Issue Number	9
Volume Number	42
Language	English
Publisher	Walter de Gruyter GmbH
Publisher Date	1987-09-01
Access Restriction	Open
Subject Keyword	Zeitschrift Für Naturforschung B Inorganic Chemistry X-ray Crystal Structures of Co- and Mn-clusters Thiolate Ligands Journal: Zeitschrift für Naturforschung B, Vol- 42
Content Type	Text
Resource Type	Article
Subject	Chemistry