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Synthesis of some Cd(II) and Zn(II) complexes of a tetraazamacrocyclic ligand and their antimicrobial activities
| Content Provider | Scilit |
|---|---|
| Author | Nath, Ranjit K Roy, Tapashi G Sutradhar, Rk |
| Copyright Year | 2017 |
| Description | Synthetic macrocycles specially the tetraazamacrocycles and their complexes have attracted considerable interests owing to their wide variety of applications. The ligand, 3, 10-C-meso- 3,5,7,7,10,12,14,14-octamethy1-1,4,8,11- $tetraazacyclotetradeca-4,11-diene(L^{1}$), upon reaction with $CdI_{2}$, $Zn(ClO_{4})_{2}$, and $Zn(CH_{3}COO)_{2}$ produces corresponding square pyramidal cadmium (II) and zinc (II) complexes of formula [ML^{1}$X]Y_{n}$, (M = Cd or Zn; X = I, $CH_{3}$COO or $H_{2}$O; Y= I, $ClO_{4}$ or $CH_{3}$COO; n = 1 or 2). Among them, $[CdL^{1}$I]I and [ZnL^{1}$(H_{2}O)](ClO_{4})_{2 }$undergo substitution reactions with KSCN and $NaNO_{2}$, respectively to produce octahedral trans- diisothiocyanatocadmium(II) complex, trans-[CdL^{1}$(NCS)_{2}$] and square pyramidal mononitratozinc(II) nitrate complex, [ZnL^{1}$(NO_{2})](NO_{2}$). Antifimgal and antibacterial activities of these complexes against some of phytopathogenic fungi and bacteria have been investigated in this study. Asian Australas. J. Biosci. Biotechnol. 2017, 2 (2), 136-144 |
| Ending Page | 144 |
| Page Count | 9 |
| Starting Page | 136 |
| ISSN | 24141283 |
| e-ISSN | 24146293 |
| DOI | 10.3329/aajbb.v2i2.64379 |
| Journal | Asian-Australasian Journal of Bioscience and Biotechnology |
| Issue Number | 2 |
| Volume Number | 2 |
| Language | English |
| Publisher | Bangladesh Academy of Sciences |
| Publisher Date | 2017-08-31 |
| Access Restriction | Open |
| Subject Keyword | Inorganic Chemistry Macrocyclic Ligand Cadmium (ii) & Zinc (ii) Complexes Antimicrobial Activities |
| Content Type | Text |
| Resource Type | Article |
