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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Clyne, M. A. A. Coxon, J. A. Woon-Fat, A. R. |
| Copyright Year | 1971 |
| Abstract | Emission has been observed from v′⩽ 9 of the B3Π(0+u) state of Br2 formed in the recombination of two ground-state Br(2P) atoms at 298 K and near 1 Torr total pressure of argon. Measurements of relative band intensities of the Br2(B→X) system have been combined with Franck-Condon factors to show that the vibrational population distribution is thermal for 298 K in the range 5 ⩽v′⩽ 9, but that the lower levels 0 ⩽v′⩽ 4 are populated to only a small extent under these conditions. The results suggest that recombination of two Br(2P) atoms into the B3II(0+u) state occurs in the vicinity of v′= 5 via a potential energy barrier of approximately 600 cm–1. |
| Starting Page | 3155 |
| Ending Page | 3165 |
| Page Count | 11 |
| File Format | |
| ISSN | 00147672 |
| Volume Number | 67 |
| Journal | Transactions of the Faraday Society |
| DOI | 10.1039/TF9716703155 |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Potential energy surface Bromine Condon Carrier generation and recombination Torr Argon |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy Physical and Theoretical Chemistry Engineering |
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