NDLI: Dual physically crosslinked double network hydrogels with high toughness and self-healing properties

Please wait, while we are loading the content...

Enhanced temperature effect of electrorheological fluid based on cross-linked poly(ionic liquid) particles: rheological and dielectric relaxation studies

Fracture of a model cohesive granular material

Simultaneous measurement of the Young's modulus and the Poisson ratio of thin elastic layers

Wrinkling of milk skin is mediated by evaporation

Closer insight into the structure of moderate to densely branched comb polymers by combining modelling and linear rheological measurements

Controlled and tunable design of polymer interface for immobilization of enzymes: does curvature matter?

Back cover

Soft Matter Vol - 13 Issue - 4

Soft Matter Vol - 13 Issue - 3

Soft Matter Vol - 13 Issue - 2

Dual physically crosslinked double network hydrogels with high toughness and self-healing properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Yang, Qian Zheng, Jie Zhao, Youjiao Li, Xuefeng Long, Shijun
Copyright Year	2017
Abstract	Toughness and self-healing properties are desirable characteristics in engineered hydrogels used for many practical applications. However, it is still challenging to develop hydrogels exhibiting both of these attractive properties in a single material. In this work, we present the fabrication of fully physically-linked Agar/PAAc-Fe3+ DN gels. These hydrogels exhibited dual physical crosslinking through a hydrogen bonded crosslinked agar network firstly, and a physically linked PAAc-Fe3+ network via Fe3+ coordination interactions secondly. Due to this dual physical crosslinking, the fabricated Agar/PAAc-Fe3+ DN gels exhibited very favorable mechanical properties (tensile strength 320.7 kPa, work of extension 1520.2 kJ m−3, elongation at break 1130%), fast self-recovery properties in Fe3+ solution (100% recovery within 30 min), in 50 °C conditions (100% recovery within 15 min), and under ambient conditions (100% recovery of the initial properties within 60 min), as well as impressive self-healing properties under ambient conditions. All of the data indicate that both the hydrogen bonds in the first network and the ionic coordination interactions in the second network act as reversible sacrificial bonds to dissipate energy, thus conferring high mechanical and recovery properties to the prepared Agar/PAAc-Fe3+ DN gels.
Starting Page	911
Ending Page	920
Page Count	10
File Format	HTM / HTML PDF
ISSN	1744683X
Volume Number	13
Issue Number	5
Journal	Soft Matter
DOI	10.1039/c6sm02567f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Toughness Agar Ultimate tensile strength Pascal (unit) Hydrogen bond
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Highly stretchable and super tough nanocomposite physical hydrogels facilitated by the coupling of intermolecular hydrogen bonds and analogous chemical crosslinking of nanoparticles

In situ polymerization induced supramolecular hydrogels of chitosan and poly(acrylic acid-acrylamide) with high toughness

A Hydrogen Bonds-Crosslinked Hydrogels With Self-Healing and Adhesive Properties for Hemostatic

Super-tough, ultra-stretchable and strongly compressive hydrogels with core–shell latex particles inducing efficient aggregation of hydrophobic chains

Self-healable, super tough graphene oxide–poly(acrylic acid) nanocomposite hydrogels facilitated by dual cross-linking effects through dynamic ionic interactions

BaTiO3/Polyurethane Dielectric Composites with Diels-Alder Bond for Improved Self-Healing Properties

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels

Aluminophosphate monoliths with high CO₂-over-N₂ selectivity and CO₂ capture capacity

Novel chitosan–cellulose nanofiber self-healing hydrogels to correlate self-healing properties of hydrogels with neural regeneration effects

Dual physically crosslinked double network hydrogels with high toughness and self-healing properties

Similar Documents

Highly stretchable and super tough nanocomposite physical hydrogels facilitated by the coupling of intermolecular hydrogen bonds and analogous chemical crosslinking of nanoparticles

In situ polymerization induced supramolecular hydrogels of chitosan and poly(acrylic acid-acrylamide) with high toughness

A Hydrogen Bonds-Crosslinked Hydrogels With Self-Healing and Adhesive Properties for Hemostatic

Super-tough, ultra-stretchable and strongly compressive hydrogels with core–shell latex particles inducing efficient aggregation of hydrophobic chains

Self-healable, super tough graphene oxide–poly(acrylic acid) nanocomposite hydrogels facilitated by dual cross-linking effects through dynamic ionic interactions

BaTiO3/Polyurethane Dielectric Composites with Diels-Alder Bond for Improved Self-Healing Properties

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels

Aluminophosphate monoliths with high CO2-over-N2 selectivity and CO2 capture capacity

Novel chitosan–cellulose nanofiber self-healing hydrogels to correlate self-healing properties of hydrogels with neural regeneration effects

Dual physically crosslinked double network hydrogels with high toughness and self-healing properties

Aluminophosphate monoliths with high CO₂-over-N₂ selectivity and CO₂ capture capacity