NDLI: Nanoscale visualization and multiscale mechanical implications of bound rubber interphases in rubber

Please wait, while we are loading the content...

The effect of ionic liquid type on the properties of hydrogenated nitrile elastomer/hydroxy-functionalized multi-walled carbon nanotube/ionic liquid composites

Aggregation-induced microgelation: a new approach to prepare gels in solution

In situ hydrogelation and RGD conjugation of tyramine-conjugated 4-arm PPO–PEO block copolymer for injectable bio-mimetic scaffolds

Bias- and bath-mediated pairing of particles driven through a quiescent medium

Liposil-supported lipid bilayers as a hybrid platform for drug delivery

Phase phenomena in supported lipid films under varying electric potential

Encapsulation studies and selective membrane permeability properties of self-assembly hollow nanospheres

Controlled drug release under a low frequency magnetic field: effect of the citrate coating on magnetoliposomes stability

Microphase separation in linear multiblock copolymers under poor solvent conditions

Solvent segregation and capillary evaporation at a superhydrophobic surface investigated by confocal Raman microscopy and force measurements

Superoleophobic behavior of fluorinated conductive polymer films combining electropolymerization and lithography

Supramolecular nanotube-based fiber mats by self-assembly of a tailored amphiphilic low molecular weight hydrogelator

Nanoscale visualization and multiscale mechanical implications of bound rubber interphases in rubber–carbon black nanocomposites

Ordered interfaces for dual easy axes in liquid crystals

Osmotically induced deformation of capsid-like icosahedral vesicles

The influence of the chemical and structural features of xylan on the physical properties of its derived hydrogels

Migration of a sphere in a viscoelastic fluid under planar shear flow: Experiments and numerical predictions

Interaction of spherical colloidal particles in nematic media with degenerate planar anchoring

Bowl- and porous sphere-shaped supramolecular assemblies and their application as templates for confined assembly of gold nanoparticles

Modification of self-assembled nanotubes by click chemistry generates new nanotubes by an out-of equilibrium process

Biomimetic triblock copolymer membranes: from aqueous solutions to solid supports

Nanoscale carbon particles and the stability of lipid bilayers

Microphase transitions of block copolymer/nanorod composites under shear flow

Self-ordered arrays of linear defects and virtual singularities in thin smectic-A films

Characterization of temperature-induced association in aqueous solutions of charged ABCBA-type pentablock tercopolymers

Time-resolved fluorescence anisotropy studies of the cononsolvency of poly(N-isopropyl acrylamide) in mixtures of methanol and water

Interplay between the thermotropic mesomorphic behavior and the microphase separation in dendron–liquid crystalline block copolymers

Structure of thin film polymer/nanoparticle systems: polystyrene (PS) coated-Au nanoparticle/tetramethyl bisphenol-A polycarbonate mixtures (TMPC)

Surface rheological behavior of gelatin/ionic liquid-type imidazolium gemini surfactant mixed systems

Unfolding collapsed polyelectrolytes in alternating-current electric fields

Mobility of fluorescently labeled polymer micelles in living cells

Vesicle capture on patterned surfaces coated with amphiphilic biopolymers

Nanoscale visualization and multiscale mechanical implications of bound rubber interphases in rubber–carbon black nanocomposites

Content Provider	Royal Society of Chemistry (RSC)
Author	Gouldstone, Andrew Robisson, Agathe Kalkhoran, Salmon M. Vliet, Krystyn J. Van Deng, Fei Qu, Meng
Copyright Year	2011
Abstract	The concept of a “bound rubber” phase extending over nanometre-scale distances from the interface of rubber-particle nanocomposites is generally accepted. However, the thickness and elastic properties of this interphase have not been confirmed by direct experimental observation. Here, we demonstrate the existence of bound rubber in hydrogenated nitrile butadiene rubber (HNBR)–carbon black composites, through direct visualization and measurement of elastic properties. Both macro- and nanoscale mechanical analyses show that the bound rubber exhibits an elastic modulus distinct from that of the rubber matrix and of the particles. Direct visualization of this bound rubber viascanning probe microscopy-based approaches requires detailed consideration of potential artifacts in contact-based analysis of viscoelastic nanocomposites. We quantify the magnitude of such contributions, and find that the bound rubber content decreases with increasing temperature, and that its stiffness exceeds that of the rubber matrix by approximately one order of magnitude. Further, the measured thickness and elastic moduli of this bound rubber are consistent with that predicted by our numerical model of a matrix–interphase–particle composite. Together, these experiments and model demonstrate that the elastic properties of nanocomposite interphases of less than 20 nm thickness can be interrogated directly.
Starting Page	1066
Ending Page	1077
Page Count	12
File Format	HTM / HTML PDF
ISSN	1744683X
Volume Number	7
Issue Number	3
Journal	Soft Matter
DOI	10.1039/c0sm00645a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Viscoelasticity Elastic modulus Carbon black Interphase Stiffness Nanocomposite Nitrile rubber 1,3-Butadiene Composite material
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Enhanced Physical and Mechanical Properties of Nitrile-Butadiene Rubber Composites with N-Cetylpyridinium Bromide-Carbon Black

Effect of interphase characteristic and property on axial modulus of carbon nanotube based composites.

Enhancement of Chloroprene/Natural/Butadiene Rubber Nanocomposite Properties Using Organoclays and Their Combination with Carbon Black as Fillers

Preparation and mechanical properties of nitrile butadiene rubber/silicate nanocomposites (2004).

Nitrile butadiene rubber composites reinforced with reduced graphene oxide and carbon nanotubes show superior mechanical, electrical and icephobic properties

Comparison studies on nitrile-butadiene rubber nanocomposites depending on the organically modified montmorillonites.

Hydrogenated Nitrile Butadiene Rubber Nanocomposites: Preparation and Properties with Special Reference to Thermal Stability

Influence of Carbon Black and Silica Fillers with Different Concentrations on Dielectric Relaxation in Nitrile Butadiene Rubber Investigated by Impedance Spectroscopy

Synergistic Effect of Partial Replacement of Carbon Black by Palm Kernel Shell Biochar in Carboxylated Nitrile Butadiene Rubber Composites.

Nanoscale visualization and multiscale mechanical implications of bound rubber interphases in rubber–carbon black nanocomposites

Similar Documents

Enhanced Physical and Mechanical Properties of Nitrile-Butadiene Rubber Composites with N-Cetylpyridinium Bromide-Carbon Black

Effect of interphase characteristic and property on axial modulus of carbon nanotube based composites.

Enhancement of Chloroprene/Natural/Butadiene Rubber Nanocomposite Properties Using Organoclays and Their Combination with Carbon Black as Fillers

Preparation and mechanical properties of nitrile butadiene rubber/silicate nanocomposites (2004).

Nitrile butadiene rubber composites reinforced with reduced graphene oxide and carbon nanotubes show superior mechanical, electrical and icephobic properties

Comparison studies on nitrile-butadiene rubber nanocomposites depending on the organically modified montmorillonites.

Hydrogenated Nitrile Butadiene Rubber Nanocomposites: Preparation and Properties with Special Reference to Thermal Stability

Influence of Carbon Black and Silica Fillers with Different Concentrations on Dielectric Relaxation in Nitrile Butadiene Rubber Investigated by Impedance Spectroscopy

Synergistic Effect of Partial Replacement of Carbon Black by Palm Kernel Shell Biochar in Carboxylated Nitrile Butadiene Rubber Composites.

Nanoscale visualization and multiscale mechanical implications of bound rubber interphases in rubber–carbon black nanocomposites