NDLI: Methanation of residual syngas after LPG synthesis: identifying the main effects on catalytic performance with Plackett

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A laboratory-scale continuous flow chlorine generator for organic synthesis

Methanation of residual syngas after LPG synthesis: identifying the main effects on catalytic performance with Plackett–Burman screening design

Decay kinetics of sensitive bioinorganic species in a SuperFocus mixer at ambient conditions

Fast colorimetric screening for visible light photocatalytic oxidation and reduction reactions

A miniature CSTR cascade for continuous flow of reactions containing solids

Adenine as an organocatalyst for the ring-opening polymerization of lactide: scope, mechanism and access to adenine-functionalized polylactide

Process analytical technology (PAT) applied to biomass valorisation: a kinetic study on the multiphase dehydration of xylose to furfural

A spray-drying continuous-flow method for simultaneous synthesis and shaping of microspherical high nuclearity MOF beads

A new methodology for the reduction of vibrational kinetics in non-equilibrium microwave plasma: application to CO₂ dissociation

The interplay between chemistry and heat/mass transfer during the fast pyrolysis of cellulose

Correction: Hydrogenation of 2-methyl-3-butyn-2-ol over a Pd/ZnO catalyst: kinetic model and selectivity study

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Reaction Chemistry & Engineering Vol - 1 Issue - 4

Reaction Chemistry & Engineering Vol - 1 Issue - 3

Reaction Chemistry & Engineering Vol - 1 Issue - 2

Reaction Chemistry & Engineering Vol - 1 Issue - 1

Methanation of residual syngas after LPG synthesis: identifying the main effects on catalytic performance with Plackett–Burman screening design

Content Provider	Royal Society of Chemistry (RSC)
Author	Bliznuk, Vitaliy Palkovits, Regina Simeonov, Kalin Krebs, Florian Baik, Joon Hyun
Copyright Year	2016
Abstract	Methanation of residual syngas as a downstream process after liquefied petroleum gas (LPG) synthesis is considered to be an attractive alternative to conventional gas separation. Seven intensively studied factors in catalyst development (ratio of Fe/Ni, metal loading, selection of Al2O3 or SiO2 as oxidic support, addition of promoters such as potassium and/or MgO, heat dissipation by diluting with inert material and two common preparation techniques (impregnation and precipitation)) were selected within a Plackett–Burman screening design and rated towards their impact on catalytic performance such as carbon monoxide and hydrocarbon conversion as well as methane and carbon dioxide selectivity. Detailed characterization of fresh and used catalysts has been carried out applying N2-physisorption, X-ray diffraction (XRD), inductively coupled plasma atomic emission spectroscopy (ICP-AES), temperature-programmed reduction (H2-TPR), and transmission electron microscopy with energy-dispersive spectroscopy (TEM/EDS) in order to confirm the results. Finally, suggestions on the preferred levels of these factors are made for development of advanced catalysts.
Starting Page	477
Ending Page	484
Page Count	8
File Format	HTM / HTML PDF
ISSN	20589883
Volume Number	1
Issue Number	5
Journal	Reaction Chemistry & Engineering
DOI	10.1039/c6re00071a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Methane Spectroscopy Methanation Membrane gas separation Hydrocarbon Carbon dioxide Liquefied petroleum gas Inductively coupled plasma atomic emission spectroscopy Physisorption Syngas Temperature-programmed reduction Transmission electron microscopy X-ray scattering techniques Carbon monoxide Burman Potassium
Content Type	Text
Resource Type	Article
Subject	Chemistry Fluid Flow and Transfer Processes Catalysis Process Chemistry and Technology

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CH4: Methane LPG: Liquefied Petroleum Gas (2013)

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Direct synthesis of LPG from syngas in a slurry phase

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Ni nanocluster on modified CeO₂–ZrO₂ nanoporous composite for tri-reforming of methane

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Regeneration of Diesel Particulate Filter Installed on Mahindra 4 Cylinder 2.1 Liter Diesel Engine

Transition metal-rich mesoporous silicas and their enhanced catalytic properties

Methanation of residual syngas after LPG synthesis: identifying the main effects on catalytic performance with Plackett–Burman screening design

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