NDLI: Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

Please wait, while we are loading the content...

Reaction Chemistry & Engineering Vol -2

Reaction Chemistry & Engineering Vol -1

Reaction Chemistry & Engineering Vol - 1 Issue - 6

Reaction Chemistry & Engineering Vol - 1 Issue - 5

Reaction Chemistry & Engineering Vol - 1 Issue - 4

Reaction Chemistry & Engineering Vol - 1 Issue - 3

Reaction Chemistry & Engineering Vol - 1 Issue - 2

Front cover

Inside front cover

Contents list

Online monitoring and analysis for autonomous continuous flow self-optimizing reactor systems

Pitfalls and benefits of in situ and operando diffuse reflectance FT-IR spectroscopy (DRIFTS) applied to catalytic reactions

Low-cost instant CO generation at room temperature using formic acid, mesyl chloride and triethylamine

Continuous photochemistry: the flow synthesis of ibuprofen via a photo-Favorskii rearrangement

Continuous supercritical route for quantum-confined GaN nanoparticles

Highly efficient and scalable chemoenzymatic syntheses of (R)- and (S)-lactaldehydes

C–O bond hydrogenolysis vs. CC group hydrogenation of furfuryl alcohol: towards sustainable synthesis of 1,2-pentanediol

The catalytic activity and chemical structure of nano MoS₂ synthesized in a controlled environment

Simple efficient one-pot synthesis of 5-hydroxymethylfurfural and 2,5-diformylfuran from carbohydrates

A monolithic 5-(pyrrolidin-2-yl)tetrazole flow microreactor for the asymmetric aldol reaction in water–ethanol solvent

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

Model-based development of an on-column PEGylation process

A reactive continuous chromatographic process for protein PEGylation

Continuous flow Buchwald–Hartwig amination of a pharmaceutical intermediate

Upgrading of bio-oil and subsequent co-processing under FCC conditions for fuel production

Back cover

Reaction Chemistry & Engineering Vol - 1 Issue - 1

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

Content Provider	Royal Society of Chemistry (RSC)
Author	Zyoud, Ahed Hilal, Hikmat S. Mansour, Waseem Hussein, Ahmad Q. Jondi, Waheed
Copyright Year	2016
Abstract	Tetra(4-pyridyl)porphyrinato-manganese(III) (MnTPyP+) ions intercalated inside nano- and micro-size natural clay powders effectively catalyzed the hydrosilylation reaction of 1-octene and tri(ethoxy)silane under mild conditions. The results showed that the homogeneous MnTPyP+ ions catalyzed the reaction where both branched and linear products were observed. Intercalation significantly enhanced both catalyst activity and selectivity. Production of the linear tri(ethoxy)silyl-1-octane as sole product was confirmed by FT-IR and NMR spectra, in the case of the intercalated catalyst. The activity enhancement was more pronounced in the case of the nano-particle supported catalyst system, with turnover frequency (TF) values up to 1200 min−1 and 85% conversion observed in less than 20 min. The intercalated catalyst systems were easy to recover and were reused three times, while retaining up to 80% of their original activity. Effects of different reaction parameters on the initial reaction rate, such as clay particle size, solvent polarity, reactant concentration, catalyst loading and temperature, were investigated. A new plausible mechanism, with evidence and justifications, is proposed.
Starting Page	194
Ending Page	203
Page Count	10
File Format	HTM / HTML PDF
ISSN	20589883
Volume Number	1
Issue Number	2
Journal	Reaction Chemistry & Engineering
DOI	10.1039/c5re00010f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Octane 1-Octene Nanoparticle Clay minerals Hydrosilylation Fourier-transform infrared spectroscopy Nuclear magnetic resonance Reaction rate Tetra Solvent Silane Catalyst support
Content Type	Text
Resource Type	Article
Subject	Chemistry Fluid Flow and Transfer Processes Catalysis Process Chemistry and Technology

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

Highly Efficient and Magnetically Recyclable Pt Catalysts for Hydrosilylation Reactions

Ru-nanoparticle deposition on naturally available clay and rice husk biomass materials—Benzene hydrogenation catalysis and synthetic strategies for green catalyst development

MnBr(CO)5 : a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

K10 montmorillonite clays as environmentally benign catalysts for organic reactions

Novel supported catalyst using metalloporphyrins intercalated inside nano-and micro-clay particles in organic reactions

Rietveld refinement and Fourier-transform infrared spectroscopic study of the dickite structure at low temperature. Clays and Clay Minerals (1993)

Catalyst and method for production of methylamines

Selective ethene homologation reaction on silica supported cobalt catalyst

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

Similar Documents

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

Highly Efficient and Magnetically Recyclable Pt Catalysts for Hydrosilylation Reactions

Ru-nanoparticle deposition on naturally available clay and rice husk biomass materials—Benzene hydrogenation catalysis and synthetic strategies for green catalyst development

MnBr(CO)5 : a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

K10 montmorillonite clays as environmentally benign catalysts for organic reactions

Novel supported catalyst using metalloporphyrins intercalated inside nano-and micro-clay particles in organic reactions

Rietveld refinement and Fourier-transform infrared spectroscopic study of the dickite structure at low temperature. Clays and Clay Minerals (1993)

Catalyst and method for production of methylamines

Selective ethene homologation reaction on silica supported cobalt catalyst

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays