NDLI: Highly selective one-step hydrogenation of nitrobenzene to cyclohexylamine over the supported 10% Ni/carbon catalysts doped with 3‰ Rh

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Highly selective one-step hydrogenation of nitrobenzene to cyclohexylamine over the supported 10% Ni/carbon catalysts doped with 3‰ Rh

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Highly selective one-step hydrogenation of nitrobenzene to cyclohexylamine over the supported 10% Ni/carbon catalysts doped with 3‰ Rh

Content Provider	Royal Society of Chemistry (RSC)
Author	Xia, Qinghua Zhao, Zhenshuang Nie, Renfeng Lu, Xinhuan Zhou, Dan Deng, Hao chen, Yang Wei, Changcheng
Copyright Year	2016
Abstract	The carbon supported 10% Ni catalysts doped with 3‰ Rh have been prepared by an impregnation method. These catalysts have been used to catalyze the one-step hydrogenation of nitrobenzene to cyclohexylamine. The results show that the 3‰ Rh–10% Ni/CSC (biocarbon) catalyst exhibits an excellent performance to achieve 100 mol% conversion of nitrobenzene and 91.6% selectivity of cyclohexylamine under reaction conditions of 3.5 MPa and 140 °C. The recycling tests reveal recyclable stability of 3‰ Rh–10% Ni/CSC. This catalyst is active for the hydrogenation of a series of electron-deficient nitrobenzenes. Some factors such as the type of carriers, the content of Ni and Rh, the type of metals and additives play important roles in controlling the selective hydrogenation.
Starting Page	15354
Ending Page	15361
Page Count	8
File Format	HTM / HTML PDF
ISSN	20462069
Volume Number	6
Issue Number	19
Journal	RSC Advances
DOI	10.1039/c5ra27202e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Nitrobenzene Cyclohexylamine Carbon Hydrogenation
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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