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CO₂ capture from biogas: absorbent selection

Content Provider	Royal Society of Chemistry (RSC)
Author	Privalova, E. Murzin, D. Yu. Rasi, S. Rintala, J. Mikkola, J.-P. Eränen, K. Mäki-Arvela, P.
Copyright Year	2013
Abstract	The development of proper biogas upgrading technology offers a viable means to utilize biogas in conventional power systems. In this paper, various molecular and ionic solvent systems were evaluated for CO2 removal from biogas in a loop reactor system. The performance of amine solutions, ionic liquids and their mixtures, amino acid salts and solutions blended with piperazine was compared in terms of their CO2 loading capacity. The experimental results revealed that addition of small amounts of piperazine can increase on average by 30 vol% the efficiency of above-mentioned solutions. The CO2 capturing capacity achieved for the most promising solvents was in the range of 50–60 L CO2/L absorbent. The regeneration of the solvent mixtures can be challenging since the solvents could loose 16–43 vol% of their initial efficiency upon CO2 release. The ionic liquid [C4mim][acetate] was found to be an efficient VOCs scrubbing media. Moreover, upon use of this ionic liquid, the amount of identified volatile organic compounds (VOCs) in the studied samples was reduced by 65 wt%, while the use of 15 wt% aqueous N-methyldiethanolamine (MDEA) resulted only in 32 wt% reduction in the amount of VOCs.
Starting Page	2979
Ending Page	2994
Page Count	16
File Format	HTM / HTML PDF
ISSN	20462069
Volume Number	3
Issue Number	9
Journal	RSC Advances
DOI	10.1039/c2ra23013e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Piperazine MDEA Biogas Volatile organic compound Solvent Methyl diethanolamine Ionic liquid
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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$CO_{2}$ Absorption from Biogas Using Piperazine-Promoted 2-Amino-2-methyl-1-propanol: Process Performance in a Packed Column

Solubility of CO2 in Water + Diethanolamine + 2-Amino-2-methyl-1-propanol

Energy Minimization in Piperazine Promoted MDEA-Based CO2 Capture Process

Technological advancements in the use of ionic liquid- membrane systems for CO₂ capture from biogas/flue gas - A review.

Combined Superbase Ionic Liquid Approach to Separate CO₂ from Flue Gas.

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Modeling and Simulation of Catalyst-aided Low Temperature CO2 Desorption from Blended Monoethanolamine (MEA) – N-Methyl-diethanolamine (MDEA) Solution

Density, viscosity, physical CO2 diffusivity, and CO2 absorption capacity of novel blended N-methyl-4-piperidinol and piperazine solvent

Removal of carbon dioxide by absorption into blended amines: kinetics of absorption into aqueous AMP/HMDA, AMP/MDEA, and AMP/piperazine solutions

CO₂ capture from biogas: absorbent selection

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$CO_{2}$ Absorption from Biogas Using Piperazine-Promoted 2-Amino-2-methyl-1-propanol: Process Performance in a Packed Column

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