NDLI: Synthesis and polymerization of C-vinyl- and N-vinyl-1,2,3-triazoles

Content Provider	Royal Society of Chemistry (RSC)
Author	Miladi, Imen Abdelhedi Addis, Daniele Bernard, Julien Drockenmuller, Eric Romdhane, Hatem Ben Beghdadi, Samir
Copyright Year	2012
Abstract	Although they have been known for decades, the synthesis and polymerization of vinyl-1,2,3-triazoles have recently gained attention driven by the spectacular development of the copper-catalyzed azide-alkyne cycloaddition, the most widely applied example of the “click” chemistry philosophy. Indeed, a broad library of vinyl-1,2,3-triazole-based monomers and polymers carrying aliphatic, aromatic, heterocyclic or functional groups has been reported so far. However, their polymerization has been scarcely reported and is subjected to a broad development in the near future. This review describes the synthesis and polymerization of vinyl-1,2,3-triazole regioisomers with respect to emerging highly efficient, robust and orthogonal chemistries as well as properties of the resulting materials and their potential for the design of smart and stimuli-responsive macromolecular objects.
Starting Page	1680
Ending Page	1692
Page Count	13
File Format	HTM / HTML PDF
ISSN	17599954
Volume Number	3
Issue Number	7
Journal	Polymer Chemistry
DOI	10.1039/c1py00446h
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Organic chemistry Cycloaddition Aliphatic compound Polymerization Library 1,2,3-Triazole Orthogonality Heterocyclic compound
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry Bioengineering Biomedical Engineering Polymers and Plastics

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