NDLI: Synthesis, electrical properties, and nanocomposites of poly(3,4-ethylenedioxythiophene) nanorods

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Polymer Chemistry Vol - 1 Issue - 7

Polymer Chemistry Vol - 1 Issue - 6

Polymer Chemistry Vol - 1 Issue - 5

Polymer Chemistry Vol - 1 Issue - 4

Polymer Chemistry Vol - 1 Issue - 3

Polymer Chemistry Vol - 1 Issue - 2

Synthesis, electrical properties, and nanocomposites of poly(3,4-ethylenedioxythiophene) nanorods

Content Provider	Royal Society of Chemistry (RSC)
Author	Weder, Christoph Mendez, James D.
Copyright Year	2010
Abstract	Cellulose nanofibers or “whiskers” derived from tunicates were coated with PEDOT:PSS to produce high-aspect-ratio nanorods with high electrical conductivity. Films made from these PEDOT:PSS whiskers have surface resistivities as low as 97 Ω/□. The nanorods were found to disperse well in polar organic solvents such as dimethylformamide, which allowed the fabrication of nanocomposites with inert host polymers such as poly(methyl methacrylate) and polystyrene. These materials display surface resistivities as low as 760 Ω/□. Due to the high aspect ratio of the PEDOT:PSS-coated whiskers (64) and the formation of well-dispersed whisker networks within the polymer matrices, these materials display a percolation threshold as low as ∼2% v/v. Using a sol–gel process, electrically conducting gels and aerogels with a density of 6.4 mg cm−3 and a surface resistivity of ∼200 kΩ/□ were also produced.
Starting Page	1237
Ending Page	1244
Page Count	8
File Format	HTM / HTML PDF
ISSN	17599954
Volume Number	1
Issue Number	8
Journal	Polymer Chemistry
DOI	10.1039/c0py00118j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Electrical resistivity and conductivity PSS Percolation threshold PEDOT Dimethylformamide Poly(3,4-ethylenedioxythiophene) Sol\u2013gel process Poly(methyl methacrylate) Polymer Polystyrene Aspect ratio
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry Bioengineering Biomedical Engineering Polymers and Plastics

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