NDLI: Metal catalysts for ε-caprolactone polymerisation

Content Provider	Royal Society of Chemistry (RSC)
Author	Redshaw, Carl Arbaoui, Abdessamad
Copyright Year	2010
Abstract	Economic pressure, environmental issues and ever increasing demand are driving the shift from oil-based polymers to those available from renewable resources. Ring opening polymerisation of cyclic esters is currently a topical field with metal complex-induced coordination/insertion type polymerisation leading the way. Such a polymerisation method offers a wide range of advantages from control over the polymer structure to kinetic enhancement; however industrially available catalysts based on tin suffer from inherent toxicity and as a result a policy change from the Food and Drug Administration (FDA) is not unrealistic. This review underlines the efforts made in the past five years or so, and shows how low toxicity metals are attracting increasing attention in the field of ε-caprolactone polymerisation.
Starting Page	801
Ending Page	826
Page Count	26
File Format	HTM / HTML PDF
ISSN	17599954
Volume Number	1
Issue Number	6
Journal	Polymer Chemistry
DOI	10.1039/b9py00334g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	FDA Caprolactone Topical medication Tin Polymer Food and Drug Administration
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry Bioengineering Biomedical Engineering Polymers and Plastics

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Metal catalysts for ε-caprolactone polymerisation