NDLI: Palladium-catalysed regioselective hydroamination of 1,3-dienes: synthesis of allylic amines

Content Provider	Royal Society of Chemistry (RSC)
Author	Beller, Matthias Banerjee, Debasis Junge, Kathrin
Copyright Year	2014
Abstract	Catalytic hydroamination of unactivated 1,3-dienes represents a sustainable and atom-economic C–N bond forming process. Here, we present a novel catalytic system consisting of Pd(cod)Cl2 in combination with DPEphos for the selective 1,4-hydroamination (anti-Markovnikov reaction) of a series of acyclic and cyclic dienes. The reactions proceed in good yields and allow for the exclusive formation of allylic amines with high regioselectivity and do not need any additives.
Starting Page	368
Ending Page	372
Page Count	5
File Format	HTM / HTML PDF
ISSN	20524129
Volume Number	1
Issue Number	4
Journal	Organic Chemistry Frontiers
DOI	10.1039/c4qo00023d
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Regioselectivity Covalent bond
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Palladium-catalysed regioselective hydroamination of 1,3-dienes: synthesis of allylic amines