NDLI: One-step exfoliation and fluorination of g-C<sub>3</sub>N<sub>4</sub> nanosheets with enhanced photocatalytic activities

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New Journal of Chemistry Vol - 41 Issue - 7

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New Journal of Chemistry Vol - 41 Issue - 5

New Journal of Chemistry Vol - 41 Issue - 4

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One-step exfoliation and fluorination of g-C₃N₄ nanosheets with enhanced photocatalytic activities

Content Provider	Royal Society of Chemistry (RSC)
Author	Shao, Yongliang Wu, Yongzhong Ma, Fukun Hao, Xiaopeng Huang, Baibiao Sun, Changlong
Copyright Year	2017
Abstract	Exfoliation and functionalisation of two-dimensional (2D) nanosheets are highly desired for the improvement of their chemical and physical properties. Herein, we propose a novel and efficient method for the preparation of fluorinated graphite carbon nitride (F-C3N4) nanosheets with enhanced photocatalytic activities. A one-step route was used to exfoliate and fluorinate the graphite carbon nitride (g-C3N4) nanosheets by using g-C3N4 powder combined with ammonium fluoride (NH4F). Through related instrumental characterisation, we confirmed that few-layered F-C3N4 nanosheets were produced successfully. Meanwhile, the enhanced hydrogen evolution rate of F-C3N4 nanosheets (477.6 µmol h−1 g−1) also confirmed the feasibility of this exfoliation method. This report not only opens up new possibilities for the rational design of metal-free F-C3N4 nanosheets with stable photochemical applications but also provides a potential method for producing functionalised 2D materials.
Starting Page	3061
Ending Page	3067
Page Count	7
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	41
Issue Number	8
Journal	New Journal of Chemistry
DOI	10.1039/c7nj00035a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Ammonium fluoride Ammonium Fluoride Hydrogen Graphite Nitride Photochemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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TiO$_{2}$/g-C$_{3}$N$_{4}$ nanosheets hybrid photocatalyst with enhanced photocatalytic activity under visible light irradiation

One-step exfoliation and fluorination of g-C₃N₄ nanosheets with enhanced photocatalytic activities

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