NDLI: Bi(iii) immobilization inside MIL-101: enhanced photocatalytic performance

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Back cover

New Journal of Chemistry Vol - 41 Issue - 5

New Journal of Chemistry Vol - 41 Issue - 4

New Journal of Chemistry Vol - 41 Issue - 3

New Journal of Chemistry Vol - 41 Issue - 2

New Journal of Chemistry Vol - 41 Issue - 1

New Journal of Chemistry Vol -39

New Journal of Chemistry Vol -29

New Journal of Chemistry Vol -0

Bi(iii) immobilization inside MIL-101: enhanced photocatalytic performance

Content Provider	Royal Society of Chemistry (RSC)
Author	Korneev, Denis V. Sokolov, Maxim N. Adonin, Sergey A. Erenburg, Simon B. Kovalenko, Konstantin A. Kvashnina, Kristina Ruban, Natalia V. Trubina, Svetlana V. Fedin, Vladimir P.
Copyright Year	2017
Abstract	A novel hybrid material Bi(III)@MIL-101 (Bi(III) = Bi-containing oxoclusters and MIL-101 = chromium(III) oxoterephthalate) was obtained by the intra-pore hydrolysis of guest bismuth(III) chloride in ammonia solution. This compound was characterized by chemical analysis, powder X-ray diffraction, nitrogen sorption and TEM techniques. According to the obtained data all Bi species are located only inside the matrix. The framework structure remains intact during all synthetic operations. The chemical nature of Bi(III)-containing clusters inside the MIL-101 matrix was suggested based on the EXAFS study. The catalytic activity of Bi(III)@MIL-101 in photodegradation of methyl red (MR) has been tested. The introduction of Bi(III)-species inside MIL-101 significantly increases the photocatalytic performance in comparison with layered BiOCl which was obtained under the same synthetic conditions without MIL-101.
Starting Page	2255
Ending Page	2260
Page Count	6
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	41
Issue Number	6
Journal	New Journal of Chemistry
DOI	10.1039/c6nj03482a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Photodegradation Extended X-ray absorption fine structure Bismuth chloride Nitrogen Composite material Hydrolysis X-ray crystallography Sorption Ammonia Transmission electron microscopy Methyl red Magnetic resonance imaging Chromium
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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