NDLI: Aligned metal oxide nanotube arrays: key-aspects of anodic TiO<sub>2</sub> nanotube formation and properties

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Aligned metal oxide nanotube arrays: key-aspects of anodic TiO₂ nanotube formation and properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Nguyen, Nhat Truong So, Seulgi Riboni, Francesca Schmuki, Patrik
Copyright Year	2016
Abstract	Over the past ten years, self-aligned TiO2 nanotubes have attracted tremendous scientific and technological interest due to their anticipated impact on energy conversion, environment remediation and biocompatibility. In the present manuscript, we review fundamental principles that govern the self-organized initiation of anodic TiO2 nanotubes. We start with the fundamental question: why is self-organization taking place? We illustrate the inherent key mechanistic aspects that lead to tube growth in various different morphologies, such as ripple-walled tubes, smooth tubes, stacks and bamboo-type tubes, and importantly the formation of double-walled TiO2 nanotubes versus single-walled tubes, and the drastic difference in their physical and chemical properties. We show how both double- and single-walled tube layers can be detached from the metallic substrate and exploited for the preparation of robust self-standing membranes. Finally, we show how by selecting specific growth approaches to TiO2 nanotubes desired functional features can be significantly improved, e.g., enhanced electron mobility, intrinsic doping, or crystallization into pure anatase at high temperatures can be achieved. Finally, we briefly outline the impact of property, modifications and morphology on functional uses of self-organized nanotubes for most important applications.
Starting Page	445
Ending Page	466
Page Count	22
File Format	HTM / HTML PDF
ISSN	20556756
Volume Number	1
Issue Number	6
Journal	Nanoscale Horizons
DOI	10.1039/c6nh00054a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Anatase Electron mobility Dopant Biocompatibility Self-organization
Content Type	Text
Resource Type	Article
Subject	Materials Science

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