NDLI: Facile construction of butadiynylene based conjugated porous polymers by cost-effective Glaser coupling

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Materials Chemistry Frontiers Vol - 1 Issue - 4

Materials Chemistry Frontiers Vol - 1 Issue - 3

Materials Chemistry Frontiers Vol - 1 Issue - 2

Materials Chemistry Frontiers Vol - 1 Issue - 1

Facile construction of butadiynylene based conjugated porous polymers by cost-effective Glaser coupling

Content Provider	Royal Society of Chemistry (RSC)
Author	Ding, Sanyuan Xie, Zhen Chen, Long Li, Yang Wei, Yabo Zhao, Xiaoyu
Copyright Year	2017
Abstract	A series of butadiynylene (BD) based conjugated microporous polymers (CMPs) were facilely synthesized using various aromatic alkyne monomers with different geometries via a Glaser coupling reaction under mild conditions. All these CMPs form gels in situ after self-polycondensation. The chemical structures, morphologies, surface areas, CO2 and CH4 uptake capacities of the freeze-dried gels were thoroughly characterized. All four CMPs have large specific surface areas (up to 1008 m2 g−1), big total pore volumes (up to 1.11 cm3 g−1), high CO2 uptake capacities (up to 3.78 mmol g−1) and high CH4 adsorption capacities (up to 0.95 mmol g−1). Bearing densely incorporated active sites (CC bonds) for the binding of metallic ions (e.g. Li+), excellent porosity, and a conjugated network structure, these BD-CMPs hold great promise for applications in gas adsorption, heavy metal accumulation, heterogeneous catalysis, lithium batteries, etc.
Starting Page	867
Ending Page	872
Page Count	6
File Format	HTM / HTML PDF
ISSN	20521529
Volume Number	1
Issue Number	5
Journal	Materials Chemistry Frontiers
DOI	10.1039/c6qm00190d
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Heterogeneous catalysis Glaser Adsorption Lithium Porosity Coupling reaction Freeze-drying Heavy metals Alkyne
Content Type	Text
Resource Type	Article

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