NDLI: Absorption spectra of substituted biphenyl and related cations in solid argon and a comparison with photoelectron spectra

Content Provider	Royal Society of Chemistry (RSC)
Author	Andrews, Lester Arlinghaus, Robert T. Payne, Christopher K.
Copyright Year	1983
Abstract	One-photon and two-photon matrix photoionization experiments have been performed with substituted biphenyls, fluorene and 9,10-dihydrophenanthrene. Absorption spectra in the red region correlate with photoelectron spectra for a π3→π6 transition and indicate a relaxation of the dihedral angle upon ionization. Sharp ultraviolet absorption spectra are assigned to π→π* transitions for the matrix-isolated cations.
Starting Page	885
Ending Page	895
Page Count	11
File Format	PDF
ISSN	03009238
Volume Number	79
Issue Number	6
Journal	Journal of the Chemical Society, Faraday Transactions 2
DOI	10.1039/F29837900885
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Absorption spectroscopy Pi6 Orionis Fluorene Dihedral angle Ionization Photoelectrochemical process Photoemission spectroscopy Ultraviolet
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Physical and Theoretical Chemistry

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Absorption spectra of substituted biphenyl and related cations in solid argon and a comparison with photoelectron spectra