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Journal of the Chemical Society, Faraday Transactions 1 Vol - 85 Issue - 5

Journal of the Chemical Society, Faraday Transactions 1 Vol - 85 Issue - 4

Journal of the Chemical Society, Faraday Transactions 1 Vol - 85 Issue - 3

Journal of the Chemical Society, Faraday Transactions 1 Vol - 85 Issue - 2

Journal of the Chemical Society, Faraday Transactions 1 Vol -79

Journal of the Chemical Society, Faraday Transactions 1 Vol -69

A cubic equation of state for mixtures containing steam

Content Provider	Royal Society of Chemistry (RSC)
Author	Lancaster, Neil M. Wormald, Christopher J.
Copyright Year	1989
Abstract	A cubic equation of state and combining rules for mixtures containing steam has been developed The equation is based on the earlier equations of Clausius, Martin and Kubic, and contains two temperature-dependent parameters, which give it enough flexibility to fit the residual properties of both steam and non-polar fluids with sufficient accuracy. Mixture properties are calculated using pseudo-critical parameters for steam and a single temperature-independent interaction parameter ξ in the combining rule Tc12=ξ(Tc1Tc2)½. For mixtures such as steam–carbon dioxide, where there is a specific interaction between the unlike components, ξ must be obtained from cross-term second virial coefficients. Where there is no specific interaction ξ is given by ξ= 2(Vc1Vc2)½Vc12–1(I1I2)½(I1+I2)–1. The equation of state fits measurements of the excess molar enthalpy HEm of mixtures containing steam at pressures of 0.1–10 Mpa, at temperatures up to at least 700 K, and allows the calculation of (p, Vm, T) properties.
Starting Page	1315
Ending Page	1326
Page Count	12
File Format	PDF
ISSN	03009599
Volume Number	85
Issue Number	6
Journal	Journal of the Chemical Society, Faraday Transactions 1
DOI	10.1039/F19898501315
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Glenn L. Martin Company The Equation Kubic Enthalpy Martin Rudolf Clausius Concentration Clausius Cubic function Mpa
Content Type	Text
Resource Type	Article
Subject	Chemistry

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