NDLI: Effect of the size of the chelate ring on the stability of cyclic exciplexes between the cadmium(5 <sup>3</sup>P<sub>1</sub>) atom and diamines

Please wait, while we are loading the content...

Kinetics of elementary reactions at low temperatures: rate constants for the reactions of OH with HCl (298 T/K  138), CH₄(298 T/K  178) and C₂H₆(298 T/K  138)

Infrared fluorescence from CO₂ laser-pumped CF₂HCl: collision dynamics of intermode energy flow

Accurate adiabatic energy surfaces for the ground and first excited states of He+2

Effect of anisotropy of polarizability of the linear quadrupole molecule on the rate of ion capture

Structures and binding energies of benzene–methane and benzene–benzene complexes. An ab initio SCF/MP2 study

Structure, bonding and vibrational modes of the p-aminophenoxyl radical and p-benzosemiquinone radical anion from ab initio molecular orbital calculations

Investigation of the electronic spectra of furfuryl- and 2-thienyl-imino derivatives of some heterocycles: molecular orbital treatment

Excited-state properties of thiaporphyrins and their dications

Dynamics of the fluorescence quenching of 1,4-dihydroxy-, 1-amino-4-hydroxy- and 1,4-diamino-9, 10-anthraquinones by aromatic hydrocarbons

¹H and ¹⁹F nuclear magnetic relaxation study of the dynamics of the hydrogen difluoride ion, FHF^–, in the α- and β-phases of caesium hydrogen difluoride

Acid–base properties of disodium 3,3′-disulfonatobenzophenone (DSB) in the ground and excited states

Effect of the size of the chelate ring on the stability of cyclic exciplexes between the cadmium(5 ³P₁) atom and diamines

Self-association of octan-1-ol in the pure liquid state and in decane solutions as observed by viscosity, self-diffusion, nuclear magnetic resonance and near-infrared spectroscopy measurements

Thermodynamics of solvation of ions. Part 6.—The standard partial molar volumes of aqueous ions at 298.15 K

Thermodynamics of coupled reactions by the analysis of chemical relaxation signals: the nickel(II)–murexide system

Phase and chemical transformations in the self-propagating wave of an exothermal reaction in a mixture of organic powders

Ionic association of alkali-metal bromides in 2-methoxyethanol

Attraction among macroions in electrolytes: a semianalytical demonstration

X-ray photoelectron spectroscopic studies on the kinetics of photoreduction of Fe^III in single-crystal K₃(Fe,Co)(CN)₆ surfaces cleaved in situ

Fourier-transform infrared photoacoustic studies of hydrogenated diamond surfaces

Infrared characterization of the hydrocarbon intermediates in the oxidation of toluene and xylenes over vanadia–titania catalysts

Effect of the composition of titania–silica on its physical and catalytic properties

Back cover

Back matter

Journal of the Chemical Society, Faraday Transactions Vol - 89 Issue - 3

Effect of the size of the chelate ring on the stability of cyclic exciplexes between the cadmium(5 ³P₁) atom and diamines

Content Provider	Royal Society of Chemistry (RSC)
Author	Nishimura, Norio Yamamoto, Shunzo Sakata, Tetsuo
Copyright Year	1993
Abstract	The cadmium(5 3P1)-sensitized luminescence of some aliphatic diamines [R2N(CH2)nNR2; R = H or CH3, n= 1–6] has been studied under the conditions of steady-state illumination at temperatures between 493 and 609 K. It was found that the diamines of n= 2, 3, 4, and 5 have two emission bands (wavelengths at the peaks of these bands are ca. 450 and 550 nm), while the diamines of n= 1 and 6 have only a short-wavelength band. These two bands were assigned to two kinds of 1 : 1 exciplex (cyclic and acyclic ones) between an excited cadmium atom and a diamine molecule. From the temperature dependence of the equilibrium constants between two exciplexes, the enthalpy and entropy changes of the equilibrium were evaluated. The stability of the cyclic exciplexes assigned to the long-wavelength band was discussed in view of the ring size of cyclic exciplexes.
Starting Page	703
Ending Page	706
Page Count	4
File Format	PDF
ISSN	09565000
Volume Number	89
Issue Number	4
Journal	Journal of the Chemical Society, Faraday Transactions
DOI	10.1039/FT9938900703
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Cadmium Diamine Aliphatic compound Enthalpy Luminescence Entropy Correlation and dependence
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Cadmium $(5^{3}P_{1})-Photosensitized$ Luminescence of Some Aliphatic Diamines

Activation Enthalpy and Entropy for the Decay of 9-Cyanophenanthrene Exciplexes

Activation Enthalpy and Entropy for the Formation of 9-Cyanophenanthrene Exciplexes

Formation of Two Exciplexes in Cadmium-Photosensitized Reaction of Aliphatic Diamines

Formation Enthalpy and Entropy of Exciplexes with Variable Extent of Charge Transfer in Solvents of Different Polarity

Dynamics and equilibrium for the formation of fluorescent Lewis acid–base exciplexes and triplexes between 9-aminophenanthrene and aliphatic amines

Mass spectrometry study of the sublimation of aliphatic dipeptides

Structure and infrared spectra of hydrocarbon interstellar dust analogs

Structural influence on the stability of mixed ligand complexes of copper(II) with aliphatic diamines and amino acids

Effect of the size of the chelate ring on the stability of cyclic exciplexes between the cadmium(5 ³P₁) atom and diamines

Similar Documents

Cadmium $(5^{3}P_{1})-Photosensitized$ Luminescence of Some Aliphatic Diamines

Activation Enthalpy and Entropy for the Decay of 9-Cyanophenanthrene Exciplexes

Activation Enthalpy and Entropy for the Formation of 9-Cyanophenanthrene Exciplexes

Formation of Two Exciplexes in Cadmium-Photosensitized Reaction of Aliphatic Diamines

Formation Enthalpy and Entropy of Exciplexes with Variable Extent of Charge Transfer in Solvents of Different Polarity

Dynamics and equilibrium for the formation of fluorescent Lewis acid–base exciplexes and triplexes between 9-aminophenanthrene and aliphatic amines

Mass spectrometry study of the sublimation of aliphatic dipeptides

Structure and infrared spectra of hydrocarbon interstellar dust analogs

Structural influence on the stability of mixed ligand complexes of copper(II) with aliphatic diamines and amino acids

Effect of the size of the chelate ring on the stability of cyclic exciplexes between the cadmium(5 3P1) atom and diamines

Effect of the size of the chelate ring on the stability of cyclic exciplexes between the cadmium(5 ³P₁) atom and diamines