Please wait, while we are loading the content...
| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Norman, R. O. C. Anderson, N. H. |
| Copyright Year | 1971 |
| Abstract | Reactions initiated by the interaction between titanium(III) ions and some N-alkylhydroxylamines have been studied by e.s.r. spectroscopy and in one case by the isolation of products and determination of the stoicheiometry. Evidence is adduced that alkylamino-radicals are formed first but react so fast that they do not reach detectable concentrations; however, the spectra of the adducts which they form with the aci-anion from nitromethane in basic solution can be observed. One of the important modes of destruction of the alkylamino-radicals involves their rearrangement to α-aminoalkyl radicals; the spectra of the latter, as their conjugate acids, can be observed in acid solution, and they can also be efficiently scavenged by radical trapping agents in both acidic and basic media. The α-aminoalkyl radicals are effective one-electron reducing agents. The cations derived from them in this process undergo solvolysis to carbonyl compounds; in one case the carbonyl compound was obtained in over 50% yield, and in another there was evidence for its reaction with more of the hydroxylamine to form an adduct which gave a further radical by oxidation. The hyperfine splitting constants of several of the radicals are discussed; of especial note is the evidence from these data that the ammonio-group in protonated α-aminoalkyl radicals is ineffective in delocalising the spin and does not induce bending of the radicals from coplanarity at the tervalent carbon atom. |
| Starting Page | 993 |
| Ending Page | 1003 |
| Page Count | 11 |
| File Format | |
| ISSN | 00456470 |
| Volume Number | 0 |
| Journal | Journal of the Chemical Society B: Physical Organic |
| DOI | 10.1039/J29710000993 |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Titanium Spectroscopy Nitromethane Carboxylic acid Solvolysis Carbonyl group Hydroxylamine Adduct Hyperfine structure Coplanarity Carbon |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Physical and Theoretical Chemistry |
National Digital Library of India (NDLI) is a virtual repository of learning resources which is not just a repository with search/browse facilities but provides a host of services for the learner community. It is sponsored and mentored by Ministry of Education, Government of India, through its National Mission on Education through Information and Communication Technology (NMEICT). Filtered and federated searching is employed to facilitate focused searching so that learners can find the right resource with least effort and in minimum time. NDLI provides user group-specific services such as Examination Preparatory for School and College students and job aspirants. Services for Researchers and general learners are also provided. NDLI is designed to hold content of any language and provides interface support for 10 most widely used Indian languages. It is built to provide support for all academic levels including researchers and life-long learners, all disciplines, all popular forms of access devices and differently-abled learners. It is designed to enable people to learn and prepare from best practices from all over the world and to facilitate researchers to perform inter-linked exploration from multiple sources. It is developed, operated and maintained from Indian Institute of Technology Kharagpur.
Learn more about this project from here.
NDLI is a conglomeration of freely available or institutionally contributed or donated or publisher managed contents. Almost all these contents are hosted and accessed from respective sources. The responsibility for authenticity, relevance, completeness, accuracy, reliability and suitability of these contents rests with the respective organization and NDLI has no responsibility or liability for these. Every effort is made to keep the NDLI portal up and running smoothly unless there are some unavoidable technical issues.
Ministry of Education, through its National Mission on Education through Information and Communication Technology (NMEICT), has sponsored and funded the National Digital Library of India (NDLI) project.
| Sl. | Authority | Responsibilities | Communication Details |
|---|---|---|---|
| 1 | Ministry of Education (GoI), Department of Higher Education |
Sanctioning Authority | https://www.education.gov.in/ict-initiatives |
| 2 | Indian Institute of Technology Kharagpur | Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project | https://www.iitkgp.ac.in |
| 3 | National Digital Library of India Office, Indian Institute of Technology Kharagpur | The administrative and infrastructural headquarters of the project | Dr. B. Sutradhar bsutra@ndl.gov.in |
| 4 | Project PI / Joint PI | Principal Investigator and Joint Principal Investigators of the project |
Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon |
| 5 | Website/Portal (Helpdesk) | Queries regarding NDLI and its services | support@ndl.gov.in |
| 6 | Contents and Copyright Issues | Queries related to content curation and copyright issues | content@ndl.gov.in |
| 7 | National Digital Library of India Club (NDLI Club) | Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach | clubsupport@ndl.gov.in |
| 8 | Digital Preservation Centre (DPC) | Assistance with digitizing and archiving copyright-free printed books | dpc@ndl.gov.in |
| 9 | IDR Setup or Support | Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops | idr@ndl.gov.in |
|
Loading...
|