NDLI: Supramolecular organogels and nanowires based on a V-shaped cyanostilbene amide derivative with aggregation-induced emission (AIE) properties

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Journal of Materials Chemistry C Vol - 1 Issue - 19

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Journal of Materials Chemistry C Vol - 1 Issue - 8

Journal of Materials Chemistry C Vol - 1 Issue - 7

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Supramolecular organogels and nanowires based on a V-shaped cyanostilbene amide derivative with aggregation-induced emission (AIE) properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhang, Yuping Shang, Hongxing Liang, Chunshuang Ma, Yao Jiang, Shimei
Copyright Year	2013
Abstract	A V-shaped cyanostilbene amide derivative (BPBIA) containing tert-butyl groups has been designed and synthesized. It was employed as building blocks to fabricate one-dimensional (1D) organic nano- or microstructures. BPBIA shows excellent self-assembling properties. First, it can readily self-assemble into gels with nanofiber structures in several kinds of organic solvents through the cooperative effect of intermolecular hydrogen bonding, π–π stacking and cyano interactions. Second, size controllable well-defined 1D nanowires with lengths up to several millimeters also have been fabricated based on the slow evaporation approach. More importantly, the individually dispersed nanowires with uniform morphology are independent of substrates and solvents. Compared with the solution, both the generated nanofibrous gels and the nanowires exhibited significantly enhanced emission, showing typical aggregation-induced emission (AIE) behavior. The single-crystal X-ray analysis provided a reasonable explanation for the formation of 1D nano- or microstructures. Thus, the molecule could provide ways for the easy fabrication of highly emissive nano- and microstructures for use in organic optoelectronics.
Starting Page	4472
Ending Page	4480
Page Count	9
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	1
Issue Number	29
Journal	Journal of Materials Chemistry C
DOI	10.1039/c3tc30545g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	AIE Amide Butyl group Nanofiber Hydrogen bond X-ray crystallography Optoelectronics
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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