NDLI: Molecular alignment and nanostructure of 1,4,5,8,9,11-hexaazatriphenylene-hexanitrile (HATCN) thin films on organic surfaces

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Journal of Materials Chemistry C Vol - 1 Issue - 5

Molecular alignment and nanostructure of 1,4,5,8,9,11-hexaazatriphenylene-hexanitrile (HATCN) thin films on organic surfaces

Content Provider	Royal Society of Chemistry (RSC)
Author	Kim, Ji Whan Lee, Jeong-Hwan Lee, Sunghun Kim, Jang-Joo Jang, Junhyuk Lee, Hyun Hwi Kim, Hyo Jung
Copyright Year	2013
Abstract	We examined the molecular alignment and nanostructure of 1,4,5,8,9,11-hexaazatriphenylene-hexanitrile (HATCN) thin films grown on organic surfaces using the grazing incidence wide angle X-ray scattering method. HATCN molecules were found to be stacked with a (00l)hex preferred orientation on organic surfaces and the orientation was maintained with increasing thickness, in contrast to growth on metal surfaces. The structural factor from the grazing incidence small-angle X-ray scattering measurement indicated that the HATCN films were formed with regularly distributed nanograins on a hydrophobic organic surface. The nanograins maintained their arrangement, even after forming a transparent electrode on the HATCN film via a sputtering process. The preferential ordering of HATCN on three different electron transporting organic materials was further examined. HATCN displayed the highest crystallinity on the 4,7-diphenyl-1,10-phenanthroline (Bphen) layer.
Starting Page	1260
Ending Page	1264
Page Count	5
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	1
Issue Number	6
Journal	Journal of Materials Chemistry C
DOI	10.1039/c2tc00331g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Nanostructure Angle of incidence (optics) Wide-angle X-ray scattering Small-angle X-ray scattering Hydrophobe Electrode Sputtering Phenanthroline
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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