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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Liu, Bing Chen, Xiang Ming Liu, Xiao Qiang |
| Copyright Year | 2016 |
| Abstract | A new n = 2 type Ruddlesden–Popper compound Sr2LaAlTiO7 was synthesized and characterized, and the microwave dielectric properties were investigated together with their microstructures. X-ray diffraction (XRD) Rietveld analysis and selected area electron diffraction (SAED) patterns confirmed that these compounds belong to the I4/mmm space group with tetragonal crystal symmetry. The lattice parameters were calculated as a = b = 3.840 Å and c = 20.270 Å. The interlayer polarization was considerably lower than that of the previously reported SrLa2Al2O7 ceramics, and a well ordered distribution of ions along the c axis was confirmed from the high resolution transmission electron microscopy (HRTEM) images. Excellent microwave dielectric properties were obtained and an optimal combination (εr = 26.5, Q × f = 110 850 GHz, τf = 2.95 ppm °C−1) was obtained for the sample sintered at 1600 °C in air for 3 h. Considering the merits of a simple preparation, less process sensitivity and, most importantly, the comparatively cheap raw materials, Sr2LaAlTiO7 ceramics could be expected as promising new candidate for ultra-low loss microwave dielectric ceramics. |
| Starting Page | 1720 |
| Ending Page | 1726 |
| Page Count | 7 |
| File Format | HTM / HTML PDF |
| ISSN | 20507526 |
| Volume Number | 4 |
| Issue Number | 8 |
| Journal | Journal of Materials Chemistry C |
| DOI | 10.1039/c5tc03653d |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Rietveld Microwave Dielectric X-ray crystallography Gerrit Rietveld Electron diffraction Iodine Space group Tetragonal crystal system Crystal structure Transmission electron microscopy Sintering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Materials Chemistry |
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