NDLI: Thienylphenothiazine integrated pyrenes: an account on the influence of substitution patterns on their optical and electroluminescence properties

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Thienylphenothiazine integrated pyrenes: an account on the influence of substitution patterns on their optical and electroluminescence properties

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Journal of Materials Chemistry C Vol - 4 Issue - 9

Journal of Materials Chemistry C Vol - 4 Issue - 8

Journal of Materials Chemistry C Vol - 4 Issue - 7

Journal of Materials Chemistry C Vol - 4 Issue - 6

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Journal of Materials Chemistry C Vol -1

Thienylphenothiazine integrated pyrenes: an account on the influence of substitution patterns on their optical and electroluminescence properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Thomas, K. R. Justin Singh, Meenu Konidena, Rajendra Kumar Jou, Jwo-Huei
Copyright Year	2016
Abstract	A new set of thienylphenothiazine-integrated pyrenes have been prepared by Stille coupling reactions in good yields and characterized by optical, electrochemical, thermal and electroluminescence investigations. The optical properties of these dyes are highly dependent on the chromophore density on the pyrene nucleus. Thus, the tetra-substituted derivative displayed the most red-shifted absorption and emission profiles among the series, indicative of an extended π-conjugation length. And the molar extinction coefficients increased progressively from mono- to tetra-substitution, attributable to the increment in the chromophore density. Interestingly, the physicochemical properties of the isomers such as 1,6- and 1,8-disubstituted derivatives remained unaltered by positional tuning. The emission profiles of the dyes are tuned from the cyan to the orange region in accordance with the chromophore substitution. All the dyes displayed positive solvatochromism in the emission spectra, whereas their absorption profiles are insensitive to solvent polarity, indicative of a more polarized excited state of the dyes. These dyes exhibited exceptional thermal stability with remarkable thermal decomposition temperatures, which fell in the range of 585–669 °C. The oxidation propensity of these dyes increases with increasing phenothiazine loading, while the LUMO is well stabilized by tetra-substitution. Solution processable multilayer OLEDs were fabricated by using the selected dyes featuring mono-, di- and tetra-substitution either as host emitters or dopants in the CBP host matrix and found to exhibit decent device performances. Intriguingly, the 1,6-substituted isomer exhibited superior performance over the 1,8-substituted isomer.
Starting Page	4246
Ending Page	4258
Page Count	13
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	4
Issue Number	19
Journal	Journal of Materials Chemistry C
DOI	10.1039/c6tc00354k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	CBP Stille Pyrene Stille reaction Electrochemistry Electroluminescence Chromophore Concentration Cyan Solvatochromism Solvent Phenothiazine Composite material Isomer
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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Thienylphenothiazine integrated pyrenes: an account on the influence of substitution patterns on their optical and electroluminescence properties