NDLI: Structural and magnetic characterization of the double perovskite Pb<sub>2</sub>FeMoO<sub>6</sub>

Content Provider	Royal Society of Chemistry (RSC)
Author	Migliori, A. Mezzadri, F. Cabassi, R. Lantieri, M. Gilioli, E. Fittipaldi, M. Solzi, M. Bolzoni, F. Manuel, P. Orlandi, F. Pernechele, C. Spina, G. Calestani, G. Merlini, M. Delmonte, D.
Copyright Year	2016
Abstract	The chemical and physical properties of the double perovskite Pb2FeMoO6 are systematically studied by means of structural and magnetic characterization. The compound crystallizes in the cubic Fmm space group, with partial cation order involving iron and molybdenum at the perovskite B site. Structural and Mössbauer characterization points to the presence of nanometer-sized antiphase domains within the ordered matrix giving rise to two iron populations, characterized by different chemical environments, with the same weight but different valence (0.3 electrons) and inequivalent magnetic anisotropy. This structural feature deeply affects the properties of the compound: Mössbauer and EPR measurements show a high-temperature superparamagnetic-like behavior ascribed to weak magnetic interactions occurring between the antiphase domains and the rest of the sample. However, below 270 K ferrimagnetic ordering of the atomic moments is observed by neutron diffraction and SQUID magnetometry, with the onset of blocked long range magnetic interactions on the Mössbauer timescale involving both the antiphase domains and the ordered matrix below 230 K. The superparamagnetic-like behavior is ascribed to the presence of low anisotropy barriers, giving rise to an extremely thin hysteresis loop at 5 K, with a very small coercive field and remnant magnetization. The observed saturation magnetization of 1.75 μB per f.u. is in agreement with the magnetic structure determined by neutron diffraction, with the two symmetry independent sites producing a ferrimagnetic resultant μS = 1.59 μB.
Starting Page	1533
Ending Page	1542
Page Count	10
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	4
Issue Number	7
Journal	Journal of Materials Chemistry C
DOI	10.1039/c5tc03529e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	EPR Perovskite Space group Ion Molybdenum Composite material Magnetic anisotropy Ferrimagnetism Neutron diffraction SQUID Magnetometer Anisotropy Hysteresis Coercivity Saturation (magnetic)
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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