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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Tu, Guoli Zhang, Jian Huang, Linquan Chen, Lingcheng Zhou, Xin Yang, Dong Ma, Shuying Li, Can |
| Copyright Year | 2014 |
| Abstract | A novel non-fullerene small molecule electron acceptor TTzBT-DCAO, which contains all electron-withdrawing units of 2,1,3-benzothiadiazole, oligothiazole and alkyl cyanoacetate, has been synthesized and characterized. Its photophysical, electrochemical, and photovoltaic properties have been investigated. The material has favorable HOMO and LUMO levels of −5.88 and −3.60 eV, and shows strong absorption in the visible spectrum up to 650 nm. The small molecule : non-fullerene bulk-heterojunction organic photovoltaics (OPVs) were constructed based on two small molecules SF8TBT and TTzBT-DCAO. The influence of the donor : acceptor composition on device performance was investigated. The open-circuit voltages of the devices are over 1.20 V, which is among the highest values reported for single-junction OPVs. The results indicate that small molecules with all electron-withdrawing units could provide a novel route to efficient solution-processed OPVs with high open-circuit voltages. |
| Starting Page | 2657 |
| Ending Page | 2662 |
| Page Count | 6 |
| File Format | HTM / HTML PDF |
| ISSN | 20507488 |
| Volume Number | 2 |
| Issue Number | 8 |
| Journal | Journal of Materials Chemistry A |
| DOI | 10.1039/c3ta14396a |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | HOMO LUMO Electron acceptor Alkyl Electrochemistry Solar cell Electronvolt Visible spectrum Organic solar cell |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Renewable Energy, Sustainability and the Environment Materials Science |
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