NDLI: NiP<sub>3</sub>: a promising negative electrode for Li- and Na-ion batteries

Content Provider	Royal Society of Chemistry (RSC)
Author	Darwiche, A. Donnadieu, B. Monconduit, L. Fullenwarth, J. Soares, A.
Copyright Year	2014
Abstract	Due to the abundance and low cost of sodium-containing precursors ambient temperature sodium ion batteries are promising for large scale grid storage. The low melting point of Na (97.7 °C) compared to 180.6 °C for Li represents a significant safety hazard for the use of Na metal anodes at ambient temperatures, which emphasizes the need for scientists and engineers to identify, design and develop new negative electrodes for Na-ion batteries. The identification of a suitable negative electrode is a crucial challenge for any further successful development of new cells, and to date efficient and competitive negative electrodes for NaB are still very rare. In this work we demonstrate that NiP3 could be a good challenger for this purpose. NiP3 based electrodes are evaluated as negative electrode materials for Li-ion batteries (LiB) and Na-ion batteries (NaB). The study of the reaction mechanism reveals the formation of a phase of composition close to Li3P and Na3P embedding Ni nanoparticles as the final reaction product after a full discharge. While the direct conversion of NiP3 into Na3P is identified for the reaction versus Na, it is still unclear whether an amorphous phase exists during the first discharge for the reaction versus Li before the conversion. Furthermore, thanks to the carboxymethyl cellulose/carbon black (CMC/CB) electrode formulation, the NiP3 electrode possesses a very promising capacity with a reversible storage capacity higher than 1000 mA h g−1 after 50 cycles for LiB and 900 mA h g−1 after 15 cycles for NaB, which represents one of the highest capacities ever sustained in Na-ion batteries.
Starting Page	2050
Ending Page	2059
Page Count	10
File Format	HTM / HTML PDF
ISSN	20507488
Volume Number	2
Issue Number	7
Journal	Journal of Materials Chemistry A
DOI	10.1039/c3ta13976j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Li Ion Electrode Reaction mechanism Carboxymethyl cellulose Carbon black Citizens band radio
Content Type	Text
Resource Type	Article
Subject	Chemistry Renewable Energy, Sustainability and the Environment Materials Science

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