NDLI: Robust porous organic polymers as efficient heterogeneous organo-photocatalysts for aerobic oxidation reactions

Content Provider	Royal Society of Chemistry (RSC)
Author	Xue, Ming Mu, Ying Liu, Xiaoming Li, Kun Zhi, Yongfeng Xia, Hong
Copyright Year	2017
Abstract	Metal-free, visible-light active and heterogeneous organic photocatalysts offer a more sustainable and environmentally friendly alternative to traditional metal-based catalysts. Here a porous organic hyper-crosslinked polymer, CF-HCP, was successfully synthesized through a facile and cost-effective process. The chemical and structural properties of CF-HCP were fully characterized by using powder X-ray diffraction analysis, Fourier transform infrared spectroscopy, 13C solid-state NMR spectroscopy, electron microscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy and nitrogen adsorption. The new three-dimensional hyper-crosslinked network possesses a high Brunauer–Emmett–Teller (BET) specific surface area up to 1200 m2 g−1 with a pore volume of 0.92 cm3 g−1, and exhibits good thermal, chemical and photochemical stability. Importantly, CF-HCP was found to be a highly effective heterogeneous photocatalyst for a wide range of organic reactions, including the oxidative coupling of primary amines, dehydrogenation of nonactive secondary amine substrates, and selective oxidation of sulfide under visible-light irradiation and using molecular oxygen as a clean oxidant. In particular, mild reaction conditions, ease of product separation by simple filtration, significant recyclability and low cost make this network material an economical and eco-friendly catalyst for the preparation of versatile organic compounds.
Starting Page	8697
Ending Page	8704
Page Count	8
File Format	HTM / HTML PDF
ISSN	20507488
Volume Number	5
Issue Number	18
Journal	Journal of Materials Chemistry A
DOI	10.1039/c7ta02205k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Fourier Emmett Polymer X-ray crystallography Infrared spectroscopy Solid-state nuclear magnetic resonance Nuclear magnetic resonance Transmission electron microscopy Thermogravimetric analysis X-ray photoelectron spectroscopy Photoemission spectroscopy Nitrogen Adsorption Specific surface area Photochemistry Photocatalysis Dehydrogenation Amine Sulfide Oxygen
Content Type	Text
Resource Type	Article
Subject	Chemistry Renewable Energy, Sustainability and the Environment Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Highly efficient removal of Cu(ii) from aqueous solution using a novel magnetic EDTA functionalized CoFe₂O₄

Ceria–zirconia modified MnO_x catalysts for gaseous elemental mercury oxidation and adsorption

Air activation by a metal-free photocatalyst for “totally-green” hydrocarbon selective oxidation

The one-step oxidation of methanol to dimethoxymethane over sulfated vanadia–titania catalysts: influence of calcination temperature

Facile synthesis of SnO₂–PbS nanocomposites with controlled structure for applications in photocatalysis

Enhanced electrocatalytic performance of interconnected Rh nano-chains towards formic acid oxidation

Fabrication of porous Fe₂O₃/PTFE nanofiber membranes and their application as a catalyst for dye degradation

Size- and support-dependent selective amine cross-coupling with platinum nanocluster catalysts

Anchoring H₃PW₁₂O₄₀ on 3-aminopropyltriethoxysilane modified graphene oxide: enhanced adsorption capacity and photocatalytic activity toward methyl orange

Robust porous organic polymers as efficient heterogeneous organo-photocatalysts for aerobic oxidation reactions

Similar Documents

Highly efficient removal of Cu(ii) from aqueous solution using a novel magnetic EDTA functionalized CoFe2O4

Ceria–zirconia modified MnOx catalysts for gaseous elemental mercury oxidation and adsorption

Air activation by a metal-free photocatalyst for “totally-green” hydrocarbon selective oxidation

The one-step oxidation of methanol to dimethoxymethane over sulfated vanadia–titania catalysts: influence of calcination temperature

Facile synthesis of SnO2–PbS nanocomposites with controlled structure for applications in photocatalysis

Enhanced electrocatalytic performance of interconnected Rh nano-chains towards formic acid oxidation

Fabrication of porous Fe2O3/PTFE nanofiber membranes and their application as a catalyst for dye degradation

Size- and support-dependent selective amine cross-coupling with platinum nanocluster catalysts

Anchoring H3PW12O40 on 3-aminopropyltriethoxysilane modified graphene oxide: enhanced adsorption capacity and photocatalytic activity toward methyl orange

Robust porous organic polymers as efficient heterogeneous organo-photocatalysts for aerobic oxidation reactions

Highly efficient removal of Cu(ii) from aqueous solution using a novel magnetic EDTA functionalized CoFe₂O₄

Ceria–zirconia modified MnO_x catalysts for gaseous elemental mercury oxidation and adsorption

Facile synthesis of SnO₂–PbS nanocomposites with controlled structure for applications in photocatalysis

Fabrication of porous Fe₂O₃/PTFE nanofiber membranes and their application as a catalyst for dye degradation

Anchoring H₃PW₁₂O₄₀ on 3-aminopropyltriethoxysilane modified graphene oxide: enhanced adsorption capacity and photocatalytic activity toward methyl orange