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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Du, Hongyu Huang, Xiangdong Du, Xuewei Tang, Min Luo, Shuiping Shen, Pei Kang |
| Copyright Year | 2016 |
| Abstract | Monodisperse alloyed PtCu nanoparticles (NPs) have been synthesized via a facile one-pot hydrothermal method. In addition, this is the first time to obtain self-assembled NPs as a hexagonal array with six-fold symmetry in the PtCu NP system. In our synthesis, oleylamine (OAM) is essential for the self-assembly of uniform PtCu NPs. These PtCu spheres have a diameter of 4.78 ± 0.28 nm with a Pt-rich skin and are evaluated as a catalyst for the methanol oxidation reaction. The activity of the PtCu nanoparticles is 34.81 mA cm−2, while that of the PtCu/C catalysts is 24.6 mA cm−2, which is about 6.216 times and 4.4 times higher than that of the Pt/C catalyst (5.6 mA cm−2). Our studies provide a simple approach to synthesize monodisperse PtCu NPs with Pt-rich skin, making it possible to develop highly active catalysts for methanol oxidation. |
| Starting Page | 1579 |
| Ending Page | 1585 |
| Page Count | 7 |
| File Format | HTM / HTML PDF |
| ISSN | 20507488 |
| Volume Number | 4 |
| Issue Number | 5 |
| Journal | Journal of Materials Chemistry A |
| DOI | 10.1039/c5ta09261b |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | NP OAM Dispersity Hydrothermal synthesis Oleylamine Order of Australia Self-assembly Methanol |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Renewable Energy, Sustainability and the Environment Materials Science |
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