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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Li, Chunzhong Jiang, Hongliang Zhu, Yihua Feng, Qian Su, Yunhe Shen, Jianhua Yang, Xiaoling |
| Copyright Year | 2013 |
| Abstract | Three-dimensional (3D) hierarchical porous Co-containing N-doped carbon materials (HP-Co-CNs) have been successfully prepared for the first time by using cyanamide as a nitrogen source and poly(vinyl alcohol) (PVA) hydrogel-based composites as in situ templates. Remarkably, the resulting HP-Co-CNs possess controllable nitrogen content, high surface area, hierarchical interconnected macro-/mesoporous structure, and a certain amount of Co-Nx moieties which could act as active sites in the oxygen reduction reaction (ORR). In studying the application of HP-Co-CNs for the ORR, the HP-Co-CNs showed excellent electrocatalytic performance for a four-electron ORR, and longer-term stability and higher methanol tolerance then the commercial Pt/C electrocatalyst in alkaline medium, highlighting the importance of macropores for diffusion and a sufficient amount of active sites related to high specific surface area for improving the ORR performance. |
| Starting Page | 12074 |
| Ending Page | 12081 |
| Page Count | 8 |
| File Format | HTM / HTML PDF |
| ISSN | 20507488 |
| Volume Number | 1 |
| Issue Number | 39 |
| Journal | Journal of Materials Chemistry A |
| DOI | 10.1039/c3ta12493b |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Three-dimensional space Carbon Nitrogen Vinyl alcohol Mesoporous material Redox Methanol Diffusion Specific surface area |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Renewable Energy, Sustainability and the Environment Materials Science |
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