NDLI: One-step hydrothermal synthesis of V1−xWxO2(M/R) nanorods with superior doping efficiency and thermochromic properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Miao, Lei Asaka, Toru Takata, Masaki Tanemura, Sakae Chen, Ru Iwamoto, Yuji Cheng, Haoliang Nishibori, Eiji Liu, Chengyan
Copyright Year	2015
Abstract	Pure phase V1−xWxO2(M/R) nanorods with superb metal–insulator transition properties were obtained in tungsten (W)-doped level ranges from 0.5 to 2.0 at% using a one-step hydrothermal treatment without additional annealing steps. The assured level of W doping greatly promotes the grain growth of pure phase vanadium oxide (VO2)(M/R) and simultaneously the phase transition temperature (Tc) is depressed as much as 103 °C per at% W for the V1−xWxO2 nanorods when x = 1.0–2.0 at%. After mixing the pure phase VO2(M) (W-doped 0.5 at%, phase transition at 47 °C) nanorods with acrylic resin, the integrated visible transmission of the VO2 composite coating on glass is up to 60.6% and the integrated solar modulation efficiency is up to 10.3%. These results mean that the superior thermochromic property will greatly favor the practical application of VO2-based smart windows.
Starting Page	3726
Ending Page	3738
Page Count	13
File Format	HTM / HTML PDF
ISSN	20507488
Volume Number	3
Issue Number	7
Journal	Journal of Materials Chemistry A
DOI	10.1039/c4ta05559d
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Pure Phase Metal\u2013insulator transition Tungsten Hydrothermal circulation Nucleic acid thermodynamics Dopant Grain growth Vanadium Phase transition Resin Thermochromism
Content Type	Text
Resource Type	Article
Subject	Chemistry Renewable Energy, Sustainability and the Environment Materials Science

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