NDLI: Neutron scattering investigation of hydrogenic species in the ammonium molybdenum bronze (NH4)0.24H0.03MoO3

Please wait, while we are loading the content...

Discotic liquid crystals of transition-metal complexes. Part 18.—Discotic liquid crystalline behaviour in phthalocyanine compounds substituted by steric hindrance groups at the core

Anderson-type ammonium hexamolybdotungstonickelates

Cation ordering in distorted perovskites (MLa)(MgTe)O₆, M = Na, K

Intercalation of organic compounds in the layered host lattice MoO₃

FTIR and Raman spectroscopic investigation of 2, 2′-bipyridine adsorption on silica, alumina, zirconia and titania

Studies of the sorption of triethyl phosphate by ion-exchanged smectite clays

X-Ray analysis of two phases in the barium borate, sodium barium borate and sodium borate ternary phase diagram

Preparation, structure and magnetic properties of a new nickel(III) oxide: YbSr₃NiO₆

Oxygen diffusion in YBa₂Cu₃O_7–δ mixed conductors: interpretation of T-jump measurements and experiments on hysteresis of conductivity

Effect of preparation methods on properties of alumina/titanias

Effect of salt concentration on the properties of poly[oxymethylene–oligo(oxyethylene)]/Mg(ClO₄)₂ polymer electrolytes

Synthesis of a new family of a comb polymers with side-chain esters and ionic conductivities of their films containing lithium trifluoromethane sulfonate

Selective removal of silicon from zeolite frameworks using sodium carbonate

Effect of composition on the lattice parameters and thermal behaviour of nickel(II)–cobalt(II) hydroxide nitrate solid solutions

Preparation of ZnO-based varistors by the sol–gel technique

Synthesis and characterization of poly(aryl ether–sulfone) and poly(tetrahydrofuran)(A–B)_N block copolymers

H₂S-sensitive thin film fabricated from hydrothermally synthesized SnO₂ sol

Photochromic behaviour in the fluorescence spectra of 1,2-bis(9-acetoxy-10-anthryl)ethane in silicate glass prepared by the sol–gel method

Study of the Ru–Mo–O and Ru–W–O phase systems; rutile solid solutions Ru_1–xM_xO₂

Novel synthetic pathway to Bi(Pb)-2223 phase with variable Ca : Sr ratio, Bi_1.7Pb_0.3Sr_4–xCa_xCu₃O_y: 1.85x2.4

Effect of drying temperature on the physical properties of titania aerogels

Back cover

Back matter

Journal of Materials Chemistry Vol - 4 Issue - 3

Journal of Materials Chemistry Vol - 4 Issue - 2

Journal of Materials Chemistry Vol -3

Neutron scattering investigation of hydrogenic species in the ammonium molybdenum bronze (NH₄)_0.24H_0.03MoO₃

Content Provider	Royal Society of Chemistry (RSC)
Author	Slade, Robert C. T. Pressman, Helen A.
Copyright Year	1994
Abstract	Incoherent inelastic neutron scattering (IINS) and quasielastic neutron scattering (QENS) have been used in investigation of the ammonium bronze (NH4)0.24H0.03MoO3. The IINS vibrational spectrum reveals the presence of NH4+(in the interlayer region of the α-MoO3 host) and hydroxy groups (in intralayer bridging positions as in the parent hydrogen bronze, H0.27MoO3). Variable-temperature QENS measurements on instruments of differing elastic energy resolutions and differing ranges of elastic scattering vector magnitude have been used in investigation of motions of the NH4+ ion. Broadenings are observed in QENS spectra over a remarkably large temperature range. In analysis of all spectra it was necessary to invoke a variable ‘static fraction’ of hydrogen, this arising from the temperature-dependent defect structures associated with incomplete filling of NH4+ sites and consequent variations in local environment of NH4+ ions. Variations in the scattering law [S(Q,ω)] at low temperature were consistent with reorientation of order >3 of a fraction of the NH4+ present and were fitted assuming a four-fold barrier. At higher temperatures, spectra were treated using the isotropic rotational diffusion model for those reorienting ions giving discernible quasielastic broadenings, this diffusion being consequent on interaction of rotations of low-energy barrier with lattice modes.
Starting Page	501
Ending Page	508
Page Count	8
File Format	PDF
ISSN	09599428
Volume Number	4
Issue Number	4
Journal	Journal of Materials Chemistry
DOI	10.1039/JM9940400501
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Neutron diffraction Ammonium Hydrogen Elastic scattering Euclidean vector Ion Isotropy Diffusion Crystal structure
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Neutron diffraction investigation of the atomic defect structure of Y-doped SrCeO₃, a high-temperature protonic conductor

Synthesis, Structure, and Decomposition of (NH4)2[Mo6Cl14] · H2O

Influence of N-H-O hydrogen bonds on the structure and properties of (K(1-x)(NH4)(x)H2PO4) proton glasses: a single crystal neutron diffraction study.

Studies on peroxomolybdates XX. Crystal structure of ammonium dodecaoxodiperoxotetramolybdate(VI)-water(1/2), (NH4)4[Mo4O12(O2)2] · 2H2O 1

Crystal structure of the mixed conductor Sr₄Fe₄Co₂O₁₃

Crystal Structure of Hydrazinium Iodide by Neutron Diffraction

Rotational diffusion in para-azoxyanisole

Crystal structure of ammonium hexaaquacobalt(II) selenate, (NH4)2Co(SeO4)2 · 6H2O, and of ammonium hexaaquazinc selenate, (NH4)2Zn(SeO4)2 · 6H2O, hydrogen bonds in two ammonium selenate Tutton’s salts

TOF neutron scattering investigations of crystal structures in K1−x(NH4)xCl (x=0.2, 0.8) mixed crystals

Neutron scattering investigation of hydrogenic species in the ammonium molybdenum bronze (NH₄)_0.24H_0.03MoO₃

Similar Documents

Neutron diffraction investigation of the atomic defect structure of Y-doped SrCeO3, a high-temperature protonic conductor

Synthesis, Structure, and Decomposition of (NH4)2[Mo6Cl14] · H2O

Influence of N-H-O hydrogen bonds on the structure and properties of (K(1-x)(NH4)(x)H2PO4) proton glasses: a single crystal neutron diffraction study.

Studies on peroxomolybdates XX. Crystal structure of ammonium dodecaoxodiperoxotetramolybdate(VI)-water(1/2), (NH4)4[Mo4O12(O2)2] · 2H2O 1

Crystal structure of the mixed conductor Sr4Fe4Co2O13

Crystal Structure of Hydrazinium Iodide by Neutron Diffraction

Rotational diffusion in para-azoxyanisole

Crystal structure of ammonium hexaaquacobalt(II) selenate, (NH4)2Co(SeO4)2 · 6H2O, and of ammonium hexaaquazinc selenate, (NH4)2Zn(SeO4)2 · 6H2O, hydrogen bonds in two ammonium selenate Tutton’s salts

TOF neutron scattering investigations of crystal structures in K1−x(NH4)xCl (x=0.2, 0.8) mixed crystals

Neutron scattering investigation of hydrogenic species in the ammonium molybdenum bronze (NH4)0.24H0.03MoO3

Neutron diffraction investigation of the atomic defect structure of Y-doped SrCeO₃, a high-temperature protonic conductor

Crystal structure of the mixed conductor Sr₄Fe₄Co₂O₁₃

Neutron scattering investigation of hydrogenic species in the ammonium molybdenum bronze (NH₄)_0.24H_0.03MoO₃