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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Fu, Xianzhi Zheng, Yi Xiao, Fangxing Wang, Fengchang |
| Copyright Year | 2012 |
| Abstract | Gold nanoparticles (GNP) passivated by dithiolated diethylenetriaminepentaacetic (DTDTPA) linkers, GNP@DTDTPA, have been synthesized. The well-defined ZnO nanocomposite (GNP@DTDTPA/ZnO) functionalized by GNP@DTDTPA was prepared via a facile and green self-assembly approach. The specific interaction mechanism responsible for the self-assembly motif was elucidated by XPS, zeta potential and FTIR analysis. The self-assembly process was established primarily by a large amount of polar functional groups such as carboxyl (COOH), carbonyl (CO), and amide (NH–CO) groups in the DTDTPA profile, which impels GNP@DTDTPA to bind intrinsically with hydroxyl groups on the ZnO surface through hydrogen bonding interactions. On the other hand, the attractive electrostatic force between the negatively charged GNP@DTDTPA and the positively charged ZnO surface also contributes to the monodispersivity of GNP@DTDTPA on the ZnO support. The GNP/ZnO obtained after calcination of GNP@DTDTPA/ZnO retains the mono-distribution of GNP and exhibits more enhanced photocatalytic and photoelectrochemical performances compared to pure ZnO. We propose a possible mechanism that the well-distributed GNP could serve as an “electron reservoir” and improve the separation efficiency of photogenerated electron–hole pairs. This method could provide a simple and straightforward approach for achieving a uniform distribution of noble-metal nanoparticles on the surface of semiconductors for versatile photocatalytic and photoelectrochemical applications. |
| Starting Page | 2868 |
| Ending Page | 2877 |
| Page Count | 10 |
| File Format | HTM / HTML PDF |
| ISSN | 09599428 |
| Volume Number | 22 |
| Issue Number | 7 |
| Journal | Journal of Materials Chemistry |
| DOI | 10.1039/c2jm15122g |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Measures of national income and output Nanocomposite Self-assembly Zeta potential Carbonyl group Amide Hydroxy group Calcination Photoelectrochemical cell Petroleum reservoir Discrete uniform distribution Noble metal |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Materials Chemistry |
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