NDLI: Sol-gel processing and structural study of europium-doped hybrid materials

Please wait, while we are loading the content...

Design of photonic liquid crystal materials: synthesis and evaluation of new chiral thioindigo dopants designed to photomodulate the spontaneous polarization of ferroelectric liquid crystals

Self-reinforcing hydrogels comprised of hydrophobic methyl methacrylate macromers copolymerised with either N-vinyl-2-pyrrolidone or 2-hydroxyethyl acrylate

NLO properties of polymeric Langmuir-Blodgett films of sulfonamide-substituted azobenzenes

N-Alkyl-p-nitroanilines: impact of alkyl chain length on crystal structures and optical SHG

‘Core and sheath' structure of a TTF complex forming a square grid

Synthesis, structure and properties of [ethylpyridinium][Ni(mnt)₂]: evidence for an unusual magnetically ordered ground state

Synthesis, polymerization and characterization of substituted dithieno[3,4-b:3′,4′-d]thiophenes

Organic-inorganic hybrid materials incorporating phosphorus centres. Evidence for some factors controlling the accessibility of phosphorus centres

Sol-gel processing and structural study of europium-doped hybrid materials

Application of organic-inorganic polymer hybrids as selective gas permeation membranes

CT complexes based on TEMPO radicals

Microemulsion mediated sol-gel synthesis of nano-scaled MAl₂O₄ (M=Co, Ni, Cu) spinels from single-source heterobimetallic alkoxide precursors

XRD, TEM and ²⁹Si MAS NMR study of sol-gel ZnO-SiO₂ nanocomposites

Aerosol-assisted chemical vapour deposition (AACVD) of silver films from triphenylphosphine adducts of silver β-diketonates and β-diketoiminates, including the structure of [Ag(hfac)(PPh₃)]

Thin film deposition of lanthanum manganite perovskite by the ALE process

Equilibrium and non-equilibrium phase diagram within the TeO₂-rich part of the TeO₂-Nb₂O₅ system

Antiferromagnetic properties of the intermetallics Ce₃Ni₂X₇(X=Ge or Sn)

Low temperature synthesis, structure and magnetic properties of La_0.85(Na_1–_xK_x)_0.15MnO₃ perovskites: the role of A cation size disparity in the electronic properties of mixed-valence manganates

Combustion synthesis of nanometal particles supported on α-Al₂O₃: CO oxidation and NO reduction catalysts

New open-framework layered tin(II) phosphates intercalated with amines

Spectroscopic characterization of (BEDT-TTF)₂[Pt(S₂C₄O₂)₂] charge density wave ground state

Solid state ²H NMR study of the orientation and dynamics of cobaltocenium intercalated in the layered silicate LaponiteRD

Preparation of lead hydroxyapatite particles using acetamide

A low-temperature route to InP nanocrystals

Experimental evidence for equilibrium surface segregation in a CoPd alloy

The use of constant rate thermal analysis (CRTA) for controlling the texture of hematite obtained from the thermal decomposition of goethite

Dye adsorption on self-assembled silane monolayers: optical absorption and modeling

Journal of Materials Chemistry Vol - 9 Issue - 7

Journal of Materials Chemistry Vol - 9 Issue - 6

Journal of Materials Chemistry Vol - 9 Issue - 5

Journal of Materials Chemistry Vol - 9 Issue - 4

Journal of Materials Chemistry Vol - 9 Issue - 3

Journal of Materials Chemistry Vol - 9 Issue - 2

Journal of Materials Chemistry Vol -8

Journal of Materials Chemistry Vol -7

Journal of Materials Chemistry Vol -6

Journal of Materials Chemistry Vol -5

Journal of Materials Chemistry Vol -4

Journal of Materials Chemistry Vol -3

Sol-gel processing and structural study of europium-doped hybrid materials

Content Provider	Royal Society of Chemistry (RSC)
Author	Almeida, A. Paula Passos de Bermudez, Verónica de Zea Smith, Michael J. Carlos, Luís D. Silva, M. Manuela
Copyright Year	1999
Abstract	The thermal, morphological and conducting properties of macromolecular organic-inorganic networks synthesized by the sol-gel process and containing a wide concentration range of europium trifluoromethanesulfonate, Eu(CF 3 SO 3 ) 3 , have been investigated. The hybrid matrix, U(2000), of these materials, classed as ureasils, includes a siliceous backbone and short polyether-based segments. The link between these components is made by urea bridges. The behaviour of the doped ureasils is significantly better than that of previously characterized electrolytes based on poly(ethylene oxide), PEO. The essentially amorphous character of the hybrid host contributes to an improved transparency and moderate conductivities of certain electrolytes at room temperature (ca. 5×10 –6 Ω –1 cm –1 ). DSC, XRD and FTIR measurements show that the formation of a high-melting crystalline complex results from the coordination of the Eu 3+ ions by the ether oxygens of the organic moieties at composition n=5 [where n represents the molar ratio of (OCH 2 CH 2 ) units per Eu 3+ ion]. The results obtained for samples with n≥20 suggest that in this range of composition the principal effect of the polyether chains is to exert a plasticizing influence, as the coordination of the cations by the urea linkages is favored.
Starting Page	1735
Ending Page	1740
Page Count	6
File Format	PDF
ISSN	09599428
Volume Number	9
Issue Number	8
Journal	Journal of Materials Chemistry
DOI	10.1039/a901587f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	DSC FTIR Eu Sol\u2013gel process Europium Composite material Urea Ethylene oxide X-ray crystallography Ether Molar mass Ion
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis, characterization and thermal properties of bentonite-polyacrylate sol–gel materials

Sol-gel Preparation and Characterizations of Europium-ion Doped Barium Magnesium Aluminate

Non-hydrolytic sol–gel process: zirconium titanate gels

Synthesis of silsesquioxane urethane hybrid materials by a modified sol–gel process

Sol-gel derived li-ion conducting polymer electrolytes.

Preparation and luminescent properties of Eu-doped BaTiO3 thin films by sol–gel process

Preparation of High Cross-linked TiO2-SiO2 Composite Material via Sol-gel Process

Viscosity Effects of the Precursor Solution and Surface Structure of Gadolinium Oxide (Gd2O3) and Gadolinium Oxide Europium Doped (Gd2O3:Eu3+) Sol-Gel Films

Preparation of whisker penetrated ceramics by internal precipitation of hollandite within a tielite matrix

Sol-gel processing and structural study of europium-doped hybrid materials

Similar Documents

Synthesis, characterization and thermal properties of bentonite-polyacrylate sol–gel materials

Sol-gel Preparation and Characterizations of Europium-ion Doped Barium Magnesium Aluminate

Non-hydrolytic sol–gel process: zirconium titanate gels

Synthesis of silsesquioxane urethane hybrid materials by a modified sol–gel process

Sol-gel derived li-ion conducting polymer electrolytes.

Preparation and luminescent properties of Eu-doped BaTiO3 thin films by sol–gel process

Preparation of High Cross-linked TiO2-SiO2 Composite Material via Sol-gel Process

Viscosity Effects of the Precursor Solution and Surface Structure of Gadolinium Oxide (Gd2O3) and Gadolinium Oxide Europium Doped (Gd2O3:Eu3+) Sol-Gel Films

Preparation of whisker penetrated ceramics by internal precipitation of hollandite within a tielite matrix

Sol-gel processing and structural study of europium-doped hybrid materials