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Front cover

Inside front cover

Contents and Chemical Science

Theme issue: inorganic nanotubes and nanowires

Devices and chemical sensing applications of metal oxide nanowires

Long range epitaxial growth of prismatic heterostructures on the facets of catalyst-free GaAs nanowires

Alternative catalysts for VSS growth of silicon and germanium nanowires

Composite-hydroxide-mediated approach as a general methodology for synthesizing nanostructures

The syntheses, properties and applications of Si, ZnO, metal, and heterojunction nanowires

ZnO-based ternary compound nanotubes and nanowires

Massive integration of inorganic nanowire-based structures on solid substrates for device applications

Properties and engineering of individual inorganic nanotubes in a transmission electron microscope

Fluid assisted assembly of one-dimensional nanoparticle array inside inorganic nanotubes

Fabrication of single crystalline gold nanobelts

Functionalized GaN nanowire-based electrode for direct label-free voltammetric detection of DNA hybridization

Epitaxial growth of hierarchical PbS nanowires

Controlled epitaxial growth modes of ZnO nanostructures using different substrate crystal planes

Carbon monoxide annealed TiO₂ nanotube array electrodes for efficient biosensor applications

Single step synthesis of Ge–SiO_x core-shell heterostructured nanowires

Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence

Synthesis, characterization, and photocatalytic properties of ZnO/(La,Sr)CoO₃ composite nanorod arrays

General surfactant-free synthesis of MTiO₃ (M = Ba, Sr, Pb) perovskite nanostrips

Low temperature, organic-free synthesis of Ba₃B₆O₉(OH)₆ nanorods and β-BaB₂O₄ nanospindles

Functionalization and solubilization of inorganic nanostructures and carbon nanotubes by employing organosilicon and organotin reagents

Seeded germanium nanowire synthesis in solution

Photoconducting response on bending of individual ZnO nanowires

Zinc oxide nanowires: controlled low temperature growth and some electrochemical and optical nano-devices

Versatile fabrication of aligned SnO₂ nanotube arrays by using various ZnO arrays as sacrificial templates

Synthesis and application of RuSe_{2 + δ} nanotubes as a methanol tolerant electrocatalyst for the oxygen reduction reaction

Fabrication of large-area hybrid nanowires arrays as novel field emitters

A general approach for synthesis of a family of functional inorganic nanotubes using highly active carbonaceous nanofibres as templates

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Seeded germanium nanowire synthesis in solution

Content Provider	Royal Society of Chemistry (RSC)
Author	Chockla, Aaron M. Korgel, Brian A.
Copyright Year	2009
Abstract	Germanium nanowires were synthesized by the thermal decomposition of diphenylgermane (DPG) in the presence of gold nanocrystals in various high boiling solvents, including squalane, squalene, octacosane, dotriacontane, and trioctylamine (TOA). The DPG decomposition chemistry was studied in these solvents. In all of the solvents except dotriacontane, DPG decomposition leads to only amorphous Ge particles unless Au nanocrystals are added to induce solution-liquid-solid (SLS) nanowire growth. In dotriacontane, crystalline nanowires were observed to form spontaneously without the addition of Au. DPG decomposes to Ge by disproportionation and in squalane and squalene the Au nanocrystals significantly increase the DPG decomposition rate. In dotriacontane, DPG decomposition was relatively fast in the absence of Au nanocrystals with the formation of crystalline nanowires, but chemical analysis of the solvent and the tips of the nanowires revealed the presence of copper and alkali and alkaline impurities that are responsible for the apparently unseeded nanowire growth.
Starting Page	996
Ending Page	1001
Page Count	6
File Format	HTM / HTML PDF
ISSN	09599428
Volume Number	19
Issue Number	7
Journal	Journal of Materials Chemistry
DOI	10.1039/b816954c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	DPG Germanium Squalene Chemistry Nanowire Disproportionation Solvent Copper Alkali metal
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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Seeded germanium nanowire synthesis in solution

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Seeded germanium nanowire synthesis in solution

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