NDLI: Spectroscopic characterization of thin solid films of a bis(chlorobenzylimidoperyleneimido)octane derivative

Content Provider	Royal Society of Chemistry (RSC)
Author	Aroca, Ricardo Duff, James Rodríguez-llorente, Santiago
Copyright Year	1998
Abstract	The synthesis, the fabrication of thin solid films and the spectroscopic characterization of a member of a new series of bis(perylene) materials, bis(chlorobenzylimidoperyleneimido)octane (BPTCDOc), are reported. The objective of the present work was to study the fabrication of submicron evaporated thin solid films of this high molecular mass perylene dye. The molecular organization of the vacuum evaporated nanometric films formed on dielectric substrates was probed using transmission infrared spectroscopy. Films fabricated on metallic surfaces were studied by reflection-absorption infrared spectroscopy (RAIRS). The fundamental vibrational modes were obtained from the FT-IR, FT-Raman and resonance Raman scattering (RRS) of isotropic solid samples. The vibrational assignment of characteristic wavenumbers is proposed. Surface-enhanced resonance Raman scattering (SERRS) allows the observation of vibrational fundamentals as well as combinations and overtones. The report includes the electronic absorption and emission spectra, extinction coefficients, monomer and excimer fluorescence.
Starting Page	629
Ending Page	632
Page Count	4
File Format	PDF
ISSN	09599428
Volume Number	8
Issue Number	3
Journal	Journal of Materials Chemistry
DOI	10.1039/a707268f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Thin Solid Films Perylene Octane Molecular mass Dye Dielectric Transmission Infrared Spectroscopy Infrared spectroscopy Fourier-transform infrared spectroscopy Resonance Raman spectroscopy Isotropy Monomer Excimer
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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