NDLI: Chemical interactions between strontium-doped praseodymium manganite and 3 mol% yttria-zirconia

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Chemical interactions between strontium-doped praseodymium manganite and 3 mol% yttria-zirconia

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhang, Jin-Ping Love, Jonathan G. Badwal, Sukhvinder P. S. Jiang, San-Ping Foger, Karl
Copyright Year	1998
Abstract	The interfacial reaction between (Pr 0.8 Sr 0.2 ) y MnO 3 (PSM, y=0.9, 1.0, 1.05) film and 3 mol% yttria tetragonal zirconia (TZ3Y) substrate has been studied at 1200 and 1400°C in air. A diffusion layer of Pr and Mn in zirconia, which was identified to be a cubic phase of zirconia, was detected in all specimens. When the solubility limit of Pr ions in the cubic zirconia was reached, a pyrochlore phase, Pr 2 Zr 2 O 7 , was formed. A delay for the formation of pyrochlore phase was observed for the A-site sub-stoichiometric and stoichiometric PSM at 1200°C. For the A-site over-stoichiometric PSM, a Pr-rich (Pr,Zr)O x phase was detected at the interface besides the pyrochlore phase. At 1400°C, a relatively thick layer of pyrochlore phase was formed after 24 hour heat treatment in all specimens. The amount of the pyrochlore phase formed at the interface depends on the A-site stoichiometry of perovskite in the initial stage. The growth of the pyrochlore layer after the initial stage, however, appears to be determined by contact area between PSM and the substrate.
Starting Page	2787
Ending Page	2794
Page Count	8
File Format	PDF
ISSN	09599428
Volume Number	8
Issue Number	12
Journal	Journal of Materials Chemistry
DOI	10.1039/a805835k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	PSM Yttrium(III) oxide Tetragonal crystal system Zirconium dioxide Diffusion Cubic zirconia Pyrochlore Zirconium Stoichiometry Perovskite
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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Characterization of intergranular phases in tetragonal and cubic yttria-stabilized zirconia

Synthesis, Structures, and Physical Properties of Yttrium-Doped Strontium Manganese Oxide Films

Reactions between Strontium-Substituted Lanthanum Manganite and Yttria-Stabilized Zirconia: I, Powder Samples

Reactions between Strontium-Substituted Lanthanum Manganite and Yttria-Stabilized Zirconia: II, Diffusion Couples

State of atoms and interatomic interactions in perovskite-type oxides: XXXIII. Interatomic interactions in lanthanum manganite doped with yttrium, calcium, and strontium (La$_{0.9}$Y$_{0.1}$Ca$_{0.5}$Sr$_{0.5}$MnO$_{3}$)

Manganese Oxide Formation in Lanthanum Strontium Manganite-Yttria-Stabilized Zirconia SOFC Cathodes

Effects of Aluminum Oxide Addition on Electrical and Mechanical Properties of 3 mol% Yttria-Stabilized Tetragonal Zirconia Electrolyte for IT-SOFCs

Room-Temperature Aging of Laminate Composites of Alumina/3-mol%-Yttria-Stablilized Tetragonal Zirconia Polycrystals

Effect of Cathode Microstructure on the Cathode Polarization in the Sintered Strontium-Doped Lanthanum Manganite/Yttria Stabilized Zirconia Solid Oxide Fuel Cells

Chemical interactions between strontium-doped praseodymium manganite and 3 mol% yttria-zirconia

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