NDLI: Optical behaviour of sodium β-aluminogallate single crystals doped with Cr3+ and Cr3+

Please wait, while we are loading the content...

Competing interactions in self-assembled monolayers containing peptide groups: molecular dynamics studies of long-chain perfluoro mercaptans on Au(111)

Molecular-modelling studies of the polypropylene catalyst

Atomistic simulation of the surface structure of spinel

Structural and defect properties of high-T_c oxides determined by atomistic lattice simulation

Calculated enthalpies of mixing of MnO/MgO and NiO/MgO

Self-consistent interatomic potentials for the simulation of binary and ternary oxides

Novel use of molecular dynamics simulation in studying structure–property relationships in the solid infrared laser medium Na⁺–Er³⁺β″-alumina

Effect of molecular polarizability distribution on the optical properties of Langmuir–Blodgett films

A highly active and highly selective oxide catalyst for the conversion of ethanol to acetone in the presence of water vapour

Liquid-crystalline palladium– and platinum–isonitrile complexes: synthesis, mesomorphic properties and molecular structure

Crystal structure of the high-temperature protonic conductor SrCeO₃

Synthesis and properties of low-molar-mass liquid-crystalline siloxane derivatives

Structural and electrochemical properties of layered manganese dioxides in relation to their synthesis: classical and sol–gel routes

Photocontrolled aggregation of colloidal silica

Structure of BiBr₂Ph: a solid-state architecture involving secondary bonding and π-π interactions

Perovskite-like intergrowth structure of the reduced cuprate Nd₂CuO_3.5: a combination of defect and excess oxygen non-stoichiometry phenomena

Space group and lattice constants for barium cerate and minor corrections to the crystal structures of BaCe_0.9Y_0.1O_2.95 and BaCe_0.9Gd_0.1O_2.95

Influence of preparation methods on the texture and structure of titania supported on silica

Optical behaviour of sodium β-aluminogallate single crystals doped with Cr³⁺ and Cr³⁺–Nd³⁺

Magnetic structure of the 4,4,4′,4′,5,5,5′,5′-octamethyl-2,2′-m-phenylenebis(4,5-dihydroimidazol-1-oxyl 3-oxide) biradical: quantum spin effect of S= 1 species associated with structural change

Neutron diffraction study of the ‘doubled perovskite’ phases Ba₂M_2–xCu_xO_4+δ(M = In, Sc)

Neutron powder diffraction study of (Bi_0.35Cu_0.65)YSr₂Cu₂O₇

Preparation and characterisation of novel polypyrrole–silica colloidal nanocomposites

X-Ray absorption spectroscopic study of the binary semiconducting glass PbV₂O₆

Preparation of aluminium nitride powder from a (hydroxo)(succinato)aluminium(III) complex

Intercalation of copper into layered lanthanum niobium oxides

Pillared layered structures vs. zeolites as sorbents and catalysts. Part 1.—Hydrocarbon separations on two alumina-pillared clays and an α-tin phosphate analogue

Solid-state and surface chemistry of CuO–TiO₂(anatase) powders

Amperometric PbSnF₄-based oxygen sensors: rapid response at room temperature in the operating pressure range 10 kPa–7.2 MPa

Investigation into the structures of some normal alkanes within the homologous series C₁₃H₂₈ to C₆₀H₁₂₂ using high-resolution synchrotron X-ray powder diffraction

Variable-temperature FTIR investigation of a laterally substituted ferroelectric liquid-crystalline benzoate

Hydrothermal synthesis and characterization of K₃Sb₃P₂O₁₄·5H₂O

Evidence for a template effect in control of organic-inorganic hybrid solid formation by intermolecular interactions

Synthesis and superconducting properties of HgBa₂Ca₂Cu₃O_{8 +x}

Editorial note. Editorial note to synthesis, crystal structure and non-linear optical properties of 2-amino-5-nitropyridine-L-(+)-tartrate, a new second-harmonic-generation crystal

Book reviews ( Journal of Materials Chemistry Vol - 4 Issue - 6 )

Back cover

Back matter

Journal of Materials Chemistry Vol - 4 Issue - 5

Journal of Materials Chemistry Vol - 4 Issue - 4

Journal of Materials Chemistry Vol - 4 Issue - 3

Journal of Materials Chemistry Vol - 4 Issue - 2

Journal of Materials Chemistry Vol -3

Optical behaviour of sodium β-aluminogallate single crystals doped with Cr³⁺ and Cr³⁺–Nd³⁺

Content Provider	Royal Society of Chemistry (RSC)
Author	Lucas, Valérie Théry, Jeanine Aka, Gérard Viana, Bruno Vivien, Daniel Kahn-Harari, Andrée
Copyright Year	1994
Abstract	Single crystals of formula Na1.6(Al0.5–xGa0.5Crx)11O17.3(x= 0.002, 0.01), were grown by the flux evaporation method. The crystal structure study shows a β-alumina type structure with strong delocalisation of Na+ ions and an inhomogeneous distribution of Ga3+. In addition to a broad and intense emission band, corresponding to the Cr(4T2→4A2) transition, the fluorescence spectra present two other signals attributed to the Cr(2E→4A2) transition of various chromium species. At 700 nm, the emission band corresponds to a D3d symmetry site and at 709 nm to a CMs symmetry site occupancy. Cr3+ pairs are also identified. Time-resolved fluorescence spectroscopy and lifetime measurements are used to determine the Cr3+ site occupancy and to study Cr3+–Cr3+ interactions.These single crystals are doped by ionic exchange in molten salts, part of the sodium being replaced by Nd3+. Studies of the Cr3+ emission and Nd3+ excitation spectra indicate that efficient Cr3+→ND3+ energy transfer takes place in this material at 300 K. From the low-temperature Nd3+ decay profile, it is suggested that the transfer occurs mainly from the 4T2 Cr3+ state, and that Cr3+ pairs do not participate significantly in this transfer.
Starting Page	907
Ending Page	913
Page Count	7
File Format	PDF
ISSN	09599428
Volume Number	4
Issue Number	6
Journal	Journal of Materials Chemistry
DOI	10.1039/JM9940400907
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Fluorescence Chromium Absorption spectroscopy Ion exchange Sodium
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Optical properties of sodium β-alumina single crystals doped with neodymium and chromium–neodymium

Energy transfer characteristics in Yb/sup 3+/-ion-doped laser materials

The Impact of Cr3+ Doping on Temperature Sensitivity Modulation in Cr3+ Doped and Cr3+, Nd3+ Co-doped Y3Al5O12, Y3Al2Ga3O12, and Y3Ga5O12 Nanothermometers

Growth and physical properties of photorefractive SBN single crystals, doped with Co, Cr, Ni

Single crystal EPR, optical absorption and superposition model study of Cr3+ doped ammonium dihydrogen phosphate.

TECHNICAL PAPERS SOLID-STATE SCIENCE AND TECHNOLOGY ESR and Optical Studies of Neodymium-Exchanged Sodium 13-Aluminogallate Single Crystals

SITE SELECTIVE SPECTROSCOPY OF Nd3+ AND Cr3+ SITES IN LiNbO3 CRYSTALS CODOPED WITH Mg2+ IONS

Growth and optical properties of Cr3+-doped CdWO4 single crystals

Upconversion of Nd3+ in Nd3+-Yb3+ Co-Doped Transparent Glass Ceramics Embededing Nano Ca5(Po4)3F Crystals

Optical behaviour of sodium β-aluminogallate single crystals doped with Cr³⁺ and Cr³⁺–Nd³⁺

Similar Documents

Optical properties of sodium β-alumina single crystals doped with neodymium and chromium–neodymium

Energy transfer characteristics in Yb/sup 3+/-ion-doped laser materials

The Impact of Cr3+ Doping on Temperature Sensitivity Modulation in Cr3+ Doped and Cr3+, Nd3+ Co-doped Y3Al5O12, Y3Al2Ga3O12, and Y3Ga5O12 Nanothermometers

Growth and physical properties of photorefractive SBN single crystals, doped with Co, Cr, Ni

Single crystal EPR, optical absorption and superposition model study of Cr3+ doped ammonium dihydrogen phosphate.

TECHNICAL PAPERS SOLID-STATE SCIENCE AND TECHNOLOGY ESR and Optical Studies of Neodymium-Exchanged Sodium 13-Aluminogallate Single Crystals

SITE SELECTIVE SPECTROSCOPY OF Nd3+ AND Cr3+ SITES IN LiNbO3 CRYSTALS CODOPED WITH Mg2+ IONS

Growth and optical properties of Cr3+-doped CdWO4 single crystals

Upconversion of Nd3+ in Nd3+-Yb3+ Co-Doped Transparent Glass Ceramics Embededing Nano Ca5(Po4)3F Crystals

Optical behaviour of sodium β-aluminogallate single crystals doped with Cr3+ and Cr3+–Nd3+

Optical behaviour of sodium β-aluminogallate single crystals doped with Cr³⁺ and Cr³⁺–Nd³⁺